硫鎓盐在可见光催化构建C—C键及C—杂原子键中的应用进展  

Recent Advances in Visible-Light-Catalyzed C—C Bonds and C—Heteroatom Bonds Formation Using Sulfonium Salts

作　　者：徐浩 张杰 左峻泽 王丰晓 吕健 混旭[1] 杨道山 Xu Hao;Zhang Jie;Zuo Junze;Wang Fengxiao;Lü Jian;Hun Xu;Yang Daoshan(College of Chemistry and Molecular Engineering,Qingdao University of Science and Technology,Qingdao,Shangdong 266042;Shandong Boyuan Pharmaceutical&Chemical Co.,Ltd.,Shouguang,Shangdong 262725;College of Chemical Engineering,Qingdao University of Science and Technology,Qingdao,Shangdong 266042)

机构地区：[1]青岛科技大学化学与分子工程学院,山东青岛266042 [2]山东博苑医药化学股份有限公司,山东寿光262725 [3]青岛科技大学化工学院,山东青岛266042

出　　处：《有机化学》2022年第12期4037-4059,共23页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.22271170)资助项目。

摘　　要：硫鎓盐是具有三个碳硫键的带正电荷的最重要四价硫化合物之一.由于硫鎓盐具有较高的化学稳定性、容易制备、结构多样、丰富的反应性等优点,其作为反应底物在有机合成中得到了广泛应用.近年来,可见光促进的有机合成方法学引起了研究者极大的兴趣.总结了各种硫鎓盐试剂在可见光诱导的自由基型反应中的研究进展,介绍了各类C—C键和C—X(X=B,N,O,S,Se,Te,F,Cl,I)键的形成反应,并对部分反应的适用范围和机理进行了讨论.Sulfonium salts are one of the most important class of organosulfur(IV)compounds which have a positive charge on the sulfur center with three C—S bonds.Because of their bench-stable,easy synthesis,broad structural diversity,and rich reactivity,sulfonium salts are playing a significant role in synthetic chemistry.In recent years,visible-light promoted photoredox catalysis is rapidly developing into a powerful tool for organic synthesis.In this paper,the recent advances of different sulfonium salts in the radical type reactions induced by visible light are summarized.The formation reactions of C—C bond and C—X(X=B,N,O,S,Se,Te,F,Cl,I)bonds are introduced,and the applicable scope and mechanism of some reactions are also discussed.

关 键 词：硫化学 硫鎓盐 可见光 自由基反应 

分 类 号：O621.251[理学—有机化学]