Cascade Synthesis of Luminescent Difluoroboron Diketonate Compounds for Room-Temperature Organic Afterglow Materials  

作　　者：Junbo Li Xuepu Wang Xiaoya Zhao Xuefeng Chen Shuhui Ding Minjian Wu Kaka Zhang 

机构地区：[1]College of Chemistry and Materials Science,Sichuan Normal University,Chengdu,Sichuan 610068,China [2]Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules,Shanghai Institute of Organic Chemistry,University of Chinese Academy of Sciences,Chinese Academy of Sciences,345 Lingling Road,Shanghai 200032,China

出　　处：《Chinese Journal of Chemistry》2022年第21期2507-2515,共9页中国化学（英文版）

基　　金：supports from theNational Natural Science Foundation of China(22175194);Shanghai Scientific and Technological Innovation Project(20QA1411600,20ZR1469200);Hundred Talents Program from Shanghai Institute of Organic Chemistry(Y121078).

摘　　要：Difluoroboronβ-diketonate(BF2bdk)compounds represent an important class of luminescent materials,whereas their synthesis requires multiple steps,which restrict their application in diverse fields.Here we report a cascade reaction to prepare BF2bdk from aromatic ketones,carboxylic acids,trifluoroacetic anhydride and boron trifluoride diethyl etherate.The cascade reaction is very simple and straightforward to produce BF2bdk with desired functional groups in reasonable isolation yields.Further,when some specific BF2bdk compounds are used as luminescent dopants,organic room-temperature phosphorescence with lifetimes>1.0 s and intense afterglow under ambient conditions can be achieved with the assistance by suitable organic matrices.The dopant-matrix materials exhibit excellent processability into desired patterns and large-area panels,and function as efficient donors of excited state energy transfer for the fabrication of red afterglow materials.

关 键 词：AFTERGLOW BORON Luminescence PHOSPHORESCENCE PHOTOPHYSICS 

分 类 号：O62[理学—有机化学]