金属有机层:制备与应用  

Metal-organic layers: Preparation and applications

作　　者：王慧锋 张超 董宝霞 钟地长 鲁统部 Huifeng Wang;Chao Zhang;Baoxia Dong;Dichang Zhong;Tongbu Lu(Institute for New Energy Materials&Low-Carbon Technologies,School of Materials Science and Engineering,Tianjin University of Technology,Tianjin 300384,China;College of Chemistry and Chemical Engineering,Yangzhou University,Yangzhou 225002,China)

机构地区：[1]Institute for New Energy Materials&Low-Carbon Technologies,School of Materials Science and Engineering,Tianjin University of Technology,Tianjin 300384,China [2]College of Chemistry and Chemical Engineering,Yangzhou University,Yangzhou 225002,China

出　　处：《Science China Materials》2023年第3期839-858,共20页中国科学（材料科学（英文版）

基　　金：supported by the National Key R&D Program of China(2017YFA0700104);the National Natural Science Foundation of China(22071182,21861001,21931007 and 21790052);the 111 Project of China(D17003);the Science&Technology Development Fund of Tianjin Education Commission for Higher Education(2018KJ129).

摘　　要：金属有机层(MOLs)以其独特的特性在材料科学中引起了广泛的关注.近十年来,MOLs在合成和应用方面发展迅速.本文综述了MOLs的最新研究进展.首先,我们介绍了MOLs的两种制备方法,即自上而下和自下而上的方法.然后,我们讨论了MOLs在气体分离、催化、能源催化和转化以及化学传感器等方面的应用,重点揭示了MOLs的性能-形貌/结构关系.最后,我们展望了MOLs在未来发展的机遇和挑战.Metal-organic layers(MOLs) have attracted considerable interest in materials science because of their unique characteristics. The past decade has witnessed the rapid development of MOLs in synthesis and applications. Here we present a review of the latest research advances on MOLs.First, we introduce the two preparation approaches for MOLs,namely, the top-down and bottom-up approaches. Then, we discuss the applications of MOLs in gas separation, catalysis,energy catalysis and conversion, and chemical sensors, which emphasize the performance-morphologies/structures relationship of MOLs. At the end of this review, we provide an outlook on the opportunities and challenges of MOLs in the future.

关 键 词：化学传感器 气体分离 材料科学 最新研究进展 自上而下 自下而上 金属有机 MOL 

分 类 号：TB34[一般工业技术—材料科学与工程]