Microstructure and phase formation of mullite-Pr6O11 composite prepared by spark plasma sintering  

作　　者：Ehsan Ghasali Davoud Ghahremani Yasin Orooji Aida Faeghi-nia Asghar Kazem-zadeh Touradj Ebadzadeh 

机构地区：[1]College of Geography and Environmental Sciences,Zhejiang Normal University,Jinhua 321004,China [2]Ceramic Dept.,Materials and Energy Research Center,Alborz,Iran [3]Department of Engineering,Maybod Branch,Islamic Azad University,Maybod,Iran

出　　处：《Journal of Rare Earths》2023年第2期283-289,共7页稀土学报（英文版）

摘　　要：The present work investigates the effect of high praseodymium oxide(Pr6O11)content on the microstructure and phase formation of mullite(3Al_(2)O_(3)·2SiO_(2))precursor by means of the spark plasma sintering process.30 wt%Pr6O11was added to a mullite precursor consisting of aluminum nitrate nonahydrate and tetraethyl orthosilicate through a high energy mixer mill in ethanol media.The spark plasma sintering was performed at a te mperature of 1200℃under 23 Pa vacuum co nditions by applying initial and final pressure of 10 and 30 MPa,respectively.XRD analysis confirms the existence of mullite,alumina,Pr6O11,Pr2O3and quartz as the only crystalline phases.FESEM images reveal an interesting deposition of hexagonal-shaped Al_(2)O_(3)particles on polished surfaces and complex oxide phases of the fiber network adhering to alumina particles in the form of tails seen on the fracture surfaces.Moreover,the bending strength of 213±21 MPa,Vickers hardness of 9.3±0.1 MPa and fracture toughness of6.21±0.12 MPa·m1/2are obtained for the prepared composite.

关 键 词：MULLITE Pr6O11 COMPOSITE Spark plasma sintering Rare earths 

分 类 号：TB33[一般工业技术—材料科学与工程]