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作 者:Yumin Zhang Jiulong Sun Xinzhe Xiao Ning Wang Guozhe Meng Lin Gu
机构地区:[1]School of Chemical Engineering and Technology,Sun Yat-sen University,Zhuhai 519082,China [2]Shenzhen Institute of Advanced Electronic Materials,Shenzhen 518100,China [3]Shenzhen Institute of Advanced Technology,Chinese Academy of Sciences,Shenzhen 518055,China
出 处:《Journal of Materials Science & Technology》2022年第34期139-162,共24页材料科学技术(英文版)
基 金:financially supported by the National Natural Science Foundation of China(No.51973231);Guangdong Basic and Applied Basic Research Foundation(Nos.2021A1515012449,2019A1515010743);the Fundamental Research Funds for the Central Universities,Sun Yat-sen University(No.20lgzd17);Open Project from State Key Laboratory of Inorganic Synthesis and Preparative Chemistry(No.2020-31)。
摘 要:In recent years, graphene has been widely employed in the field of metal corrosion protection owing to its outstanding impermeability and chemical stability, with examples of such metal protection including pure graphene coatings and graphene-based composite coatings. But the conductive graphene could promote the electrochemical reaction at the interface and accelerate the corrosion of metal substrates. More emerging graphene-like 2D nanosheets are attracting research attention for the application of metal anticorrosion, because of their barrier properties and poor conductivity, mainly including boron nitride(BN),molybdenum disulfide(MoS_(2)), zirconium phosphate(ZrP), and titanium carbide(MXene). In this review,the application of these graphene-like 2D nanosheets to metal protection is comprehensively reviewed.First, the general preparation methods of 2D nanosheets are briefly introduced. Second, surface functionalization of 2D nanosheets, including covalent and non-covalent modification, is described in detail.Third, the anticorrosion performance and optimization measures of pure 2D nanosheets coatings are summarized. Next, the protection performance, anticorrosive mechanism, and optimizations of 2D nanosheets composite coatings are presented. Finally, the future development of 2D nanosheets-based anticorrosive coatings has been prospected, and the challenges in the industrial application are discussed.
关 键 词:Two-dimensional nanomaterials Surface functionalization Polymer composite coatings Metal Corrosion protection
分 类 号:TG174.4[金属学及工艺—金属表面处理] TB383.1[金属学及工艺—金属学]
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