胶束在Suzuki和Heck偶联反应中应用  

Application of micellar catalysis in Heck and Suzuki coupling reaction

作　　者：王文权 刘萌 舒阳腾 刘全[1] Wang Wenquan;Liu Meng;Shu Yangteng;Liu Quan(College of Chemical&Environment Science,Shaanxi University of Technology,Hanzhong 723000,China)

机构地区：[1]陕西理工大学化学与环境科学学院,陕西汉中723000

出　　处：《宁波化工》2023年第1期7-14,共8页Ningbo Chemical Industry

基　　金：陕西理工大学大创项目(SLGHX2022010)。

摘　　要：随着合成化学的快速发展,合成技术愈加先进,但带来的环境污染也逐渐增加,绿色、高效、低污染的合成方法及溶剂急需应用至合成化学中,水作为理想溶剂,对环境无污染,廉价易得,在水中有机物展现出极差的溶解性,而表面活性剂作为两亲物质,可以增加有机物在水中的溶解性,进而使得反应得以进行,因此,本文介绍了胶束催化有机反应的优势,常用的表面活性剂和胶束在Suzuki和Heck反应中的应用。With the rapid development of synthetic chemistry,the synthesis technology has become more and more advanced,but the environmental pollution has also gradually increased.Green,efficient and low-pollution synthesis methods and solvents are urgently needed to be applied to synthetic chemistry.Water as an ideal solvent,has no pollution to the environment,is cheap and easy to obtain,and organic matter in water shows extremely poor solubility,while surfactant as an amphiphilic substance can increase the solubility of organic matter in water,Therefore,this paper introduces the advantages of micellar-catalyzed organic reactions and the application of commonly used surfactants and micelles in Suzuki and Heck reactions.

关 键 词：表面活性剂 胶束 SUZUKI反应 HECK反应 

分 类 号：O643.3[理学—物理化学]