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作 者:姚军强 刘媛 郑晓宇 李灿 吴志跃 董仁杰[1,2] 乔玮 YAO Junqiang;LIU Yuan;ZHENG Xiaoyu;LI Can;WU Zhiyue;DONG Renjie;QIAO Wei(College of Engineering,China Agricultural University,Beijing 100083,China;Research&Development Center for Efficient Production and Comprehensive Utilization of Biobased Gaseous Fuels,Energy Authority,National Development and Reform Committee,Beijing 100083,China;Everbright Environmental Protection(China)Co.,Ltd,Shenzhen 518033,China;Everbright Environmental Protection Technology Research Institute(Nanjing)Co.,Ltd,Nanjing 210007,China)
机构地区:[1]中国农业大学工学院,北京100083 [2]国家能源生物燃气高效制备及综合利用技术研发(实验)中心,北京100083 [3]光大环保(中国)有限公司,广东深圳518033 [4]光大环保技术研究院(南京)有限公司,南京210007
出 处:《环境工程》2022年第12期121-127,共7页Environmental Engineering
基 金:国家自然科学基金项目(51778616)。
摘 要:厌氧消化是垃圾渗滤液处理的重要技术,常规厌氧工艺在处理过程中存在微生物易流失和出水水质较差等问题。采用厌氧膜生物反应器在中温条件下处理垃圾渗滤液,考察了废水降解性能和膜过滤性能。连续100 d的反应器运行实验表明:在水力停留时间为10 d,COD容积负荷平均为5.63 kg/(m^(3)·d)的条件下,系统运行稳定,平均COD去除率达到92%,膜出水总挥发性脂肪酸浓度低于200 mg/L,pH稳定在7.95左右。在膜通量为6 L/(m^(2)·h)下,连续62 d内的膜压增长缓慢,未出现明显的膜污染。批次产甲烷试验结果表明:渗滤液产甲烷潜能达到305 mL/g TS,与连续运行实验296 mL/g TS的产气效果接近,沼气中甲烷浓度可高达70%~80%。产气达到90%和95%的潜能分别用时2.5,3.1 d,说明反应器有进一步缩短水力停留时间的可能性。反应器驯化的厌氧活性污泥对乙酸有较好的耐受性,在乙酸浓度为10000 mg/L时,产气迟滞期仅为1.4 d。综合来看,长期运行厌氧膜生物反应器处理垃圾渗滤液具有较好的COD去除效果、运行稳定性和膜过滤性。Anaerobic digestion is an important technology for landfill leachate treatment.There are some problems in the conventional anaerobic process,such as easy loss of microorganisms and poor effluent quality.In this paper,landfill leachate was treated by an anaerobic membrane bioreactor at medium temperature,and the degradation performance and membrane filtration performance of wastewater was investigated.The experimental results showed that the system ran stably under the conditions of hydraulic retention time of 10 days and volume load of 5.63 kg/(m^(3)·d).The average COD removal rate reached 92%,the total volatile fatty acid concentration of membrane effluent was less than 200 mg/L,and the pH value was stable at about 7.95.At a membrane flux of 6 L/(m^(2)·h),the membrane pressure increased slowly in 62 consecutive days without obvious membrane fouling.Batch methane production test results showed that the methane production potential of leachate reached 305 mL/g TS,being close to the gas production effect of 296 mL/g TS in the continuous running experiment.Methane concentration in biogas was high,up to 70%~80%.It took 2.5 days to reach 90%and 3.1 days to reach 95%of the total potential,respectively,indicating that the reactor had the possibility of further shorting the hydraulic retention time.The acclimated anaerobic activated sludge in the reactor had a good tolerance to acetic acid.When the acetic acid concentration was 10000 mg/L,the gas production lag period was only 1.4 days.In general,the long-term operation of the anaerobic membrane bioreactor has good COD removal effect,operation stability and membrane filtration performance when treating landfill leachate.
关 键 词:厌氧膜生物反应器 垃圾渗滤液 运行性能 膜过滤性能
分 类 号:X703[环境科学与工程—环境工程]
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