含七元碳环的多环芳烃的合成及其光电磁功能  

Synthesis and opto-electronic-magnetic functions of polycyclic aromatic hydrocarbons containing seven-membered carbon rings

作　　者：秦丽园 黄雁鹰 舒屹林 马俊龙 张西沙 张德清[1,2] Liyuan Qin;Yanying Huang;Yilin Shu;Junlong Ma;Xi-Sha Zhang;Deqing Zhang(Institute of Chemistry,Chinese Academy of Sciences,Beijing National Laboratory for Molecular Sciences,Beijing 100190,China;School of Chemical Sciences,University of Chinese Academy of Sciences,Beijing 100049,China)

机构地区：[1]中国科学院化学研究所,北京分子科学国家研究中心,北京100190 [2]中国科学院大学化学科学学院,北京100049

出　　处：《中国科学：化学》2023年第3期423-438,共16页SCIENTIA SINICA Chimica

基　　金：国家自然科学基金(编号:22071254,21790363,22021002);中国科学院青年创新促进会资助。

摘　　要：非苯型多环芳烃(polycyclic aromatic hydrocarbons,PAHs)具有不同于苯型多环芳烃的独特物理化学性质.其中,含七元碳环的非苯型多环芳烃在过去的十多年中引起了合成化学家的研究兴趣并且作为新的共轭单元被应用于有机光电材料的研究.本文主要总结和讨论了近五年来该领域取得的新进展,包括非苯型多环芳烃中构建七元碳环的新合成方法以及该类共轭分子在有机半导体、手性光学材料及磁性材料等领域中的应用,并对该领域的发展进行了展望.Non-benzenoid polycyclic aromatic hydrocarbons(PAHs)have unique physicochemical properties that are different from benzenoid PAHs.Non-benzenoid PAHs containing seven-membered carbon rings have attracted much attention from synthetic chemists in the past decades and have been used as new building blocks in organic optoelectronic materials.In this review,we summarized and discussed the recent progress in this field,including the new synthetic methods for constructing seven-membered carbon rings in non-benzenoid PAHs reported in recent years,and the applications of these conjugated molecules in organic semiconductors,chiral optical materials and magnetic materials.

关 键 词：七元碳环 多环芳烃 有机半导体 手性光学 自由基及磁性材料 

分 类 号：O625.1[理学—有机化学]