生物油及其衍生物催化重整制氢研究进展  

Research progress on catalytic reforming of bio-oil and its derivatives for hydrogen production

作　　者：李果 张安东[1,2] 万震 李志合 王绍庆[1,2] 李宁 张鹏[1,2] LI Guo;ZHANG An-dong;WAN Zhen;LI Zhi-he;WANG Shao-qing;LI Ning;ZHANG Peng(School of Agricultural Engineering and Food Science,Shandong University of Technology,Zibo 255000,China;Shandong Research Center of Engineering and Technology for Clean Energy,Shandong University of Technology,Zibo 255000,China)

机构地区：[1]山东理工大学农业工程与食品科学学院,山东淄博255000 [2]山东省清洁能源工程技术研究中心,山东淄博255000

出　　处：《燃料化学学报（中英文）》2023年第4期444-457,共14页Journal of Fuel Chemistry and Technology

基　　金：国家重点研发计划(2019YFD1100602);国家自然科学基金(52176192);山东省自然科学基金(ZR2021ME035,ZR2021QE132)资助。

摘　　要：氢气作为最理想的清洁能源之一,在石油、化工、冶金、石化、食品和化肥工业等行业中发挥着重要作用。生物油水蒸气催化重整制氢作为一种具有发展前景且经济可行的绿色制氢技术,近些年来受到了研究者的广泛关注。本工作对近年来该领域的研究进展进行综述,重点分析了生物油(生物原油、水相生物油以及重质生物油/焦油)、生物油模型化合物(羧酸类、醇类、酚类等)和其他生物油衍生物的催化重整产氢过程,包括其在重整反应机理、重整工艺以及催化剂等方面的研究进展。对多种混合模化物以及真实生物油催化重整反应机理的深入探究是目前研究的主要难点,研制节能、高效的催化重整反应器以及开发稳定、高活性的重整催化剂是目前乃至今后生物油催化重整制氢领域研究和推广的重点。Hydrogen is considered to be one of the most desirable clean energy sources and plays an important role in petroleum,chemical,metallurgical,petrochemical,food and fertilizer industries.Steam catalytic reforming of bio-oil for hydrogen production is considered as a promising and economically viable sustainable green hydrogen production technology,which has received a lot of attention from researchers.This paper presents a review of recent research in this field,focusing on the catalytic reforming of bio-oils(bio-crude oil,aqueous bio-oil and heavy bio-oil/tar),bio-oil model compounds(carboxylic acids,alcohols,phenols,etc.)and other bio-oil derivatives for hydrogen production,including the reforming reaction mechanism,reforming process and catalysts.The development of energy-efficient and efficient catalytic reforming reactors and stable and highly active reforming catalysts are the main focus of current and future research and promotion in the field of catalytic reforming of bio-oil for hydrogen production.

关 键 词：生物油 模化物 催化剂 重整制氢 

分 类 号：TK6[动力工程及工程热物理—生物能]