基于化学键开合理论的晶体溶解机理研究  

Study on Crystal Dissolution Mechanism Based on Chemical Bond Open-closing Theory

作　　者：樊丽辉 Fan Lihui(Hebei Highway Transportation Science Institute,Shij iazhang 050091;Hebei Transportation Survey,Design and Research Institute,Shijiazhang 050091)

机构地区：[1]河北省交通科学研究所,石家庄050091 [2]河北省交通勘察设计研究院,石家庄050091

出　　处：《河北交通教育》2022年第4期52-57,共6页Hebei Traffic Education

摘　　要：文中基于化学键开合理论,以及常态键和暂态键作用原理,初步阐释了原子、分子和离子间作用机制与物理特征,然后,从结构化学层面分析了晶体溶解和分子解离等,以及水合物的团簇构型、物理属性及相互作用原理,基本厘清了晶体溶解机理,并提出以价键形式揭示其规律性问题。最后,提出“广义性溶解”概念,揭示了有机物的耐候性问题,并以反氢键作用原理揭示了有机分子之间,及其与水分子之间、气体分子之间等的相互作用机制。Based on Chemical Bond Open-closing Theory(CBOC),as well as the principles of steady-bond and transient-bond interaction,this paper explains the interaction mechanism and physical characteristics among atomic,molecular and ions.Then,from the perspective of structural chemistry,it also analyzes the crystal dissolution and molecular dissociation,as well as the cluster configuration,physical properties and interaction principle of hydrate.The crystal dissolution mechanism is basically clarified,and the problem of revealing its regularity in the form of valence bond is proposed.Finally,the concept of"generalized dissolution"is put forward to reveal the weather resistance of organic compounds,and the interaction mechanism between organic molecules,water molecules and gas molecules is revealed based on the principle of anti-hydrogen bonding.

关 键 词：化学键 常态 暂态 溶解机理 价键形式 

分 类 号：O611.6[理学—无机化学]