二氧化碳加氢合成甲醇氧化铟及其负载金属催化剂研究进展  

Research progresses on In_(2)O_(3) and In_(2)O_(3) supported metal catalysts for CO_(2) hydrogenation to methanol

作　　者：沈辰阳 孙楷航 张月萍[2] 刘昌俊 SHEN Chenyang;SUN Kaihang;ZHANG Yueping;LIU Changjun(Collaborative Innovation Center of Chemical Science and Engineering,School of Chemical Engineering,Tianjin University,Tianjin 300350,China;School of Science,Tianjin University,Tianjin 300350,China)

机构地区：[1]天津大学化工学院,天津化学化工协同创新中心,天津300350 [2]天津大学理学院,天津300350

出　　处：《化工学报》2023年第1期145-156,共12页CIESC Journal

基　　金：国家自然科学基金重点项目(22138009);中央高校基本科研业务费专项资金项目。

摘　　要：二氧化碳转化利用技术在“双碳”目标达成方面将发挥重要作用。在各种转化利用反应途径中,因为甲醇可以作为有机合成中间体和液态燃料,二氧化碳加氢合成甲醇受到广泛关注。开发高活性、高选择性催化剂是二氧化碳加氢合成甲醇技术发展的关键。近年来,氧化铟及其负载金属催化剂因其高活性、高甲醇选择性而备受关注。氧化铟与一些金属,如金、银、铂、钯、钌、铑、铱、镍、铼等有强相互作用,不仅可以稳定氧化铟、避免氧化铟过还原,还导致催化剂电子结构、反应途径等发生变化,也使得一些本身不具CO_(2)加氢合成甲醇活性的金属催化剂变为高活性催化剂。CO_(2)加氢合成甲醇氧化铟系催化剂是通过理论研究预测后经实验证实发现的。CO_(2)加氢合成甲醇氧化铟及其负载金属催化剂涵盖单原子催化、团簇及纳米颗粒催化剂,是理论可预测的、难得的模型催化剂体系。相关反应途径可用于解释“催化剂”定义。CO_(2)加氢合成甲醇氧化铟及其负载金属催化剂研究在基础研究和应用两方面都具有重要意义。The conversion and utilization of carbon dioxide plays important roles in carbon neutrality.Among various options for CO_(2)utilization,hydrogenation of CO_(2)to methanol attracts increasing attentions because methanol is an important chemical intermediate and also excellent alternative liquid fuel.A highly active catalyst with high methanol selectivity is the key for the potential application of CO_(2)hydrogenation to methanol.With their high activity and high methanol selectivity,In_(2)O_(3)and In_(2)O_(3)supported metal catalysts have recently received broad interests.In_(2)O_(3)has strong interaction with metal like gold,silver,platinum,palladium,ruthenium,rhodium,iridium,nickel and rhenium.The strong metal-In_(2)O_(3)interaction can not only stabilize indium oxide,avoid over-reduction of indium oxide,but also lead to the catalyst electronic structure changes,tuning the catalyst to be highly active for selective hydrogenation of CO_(2)to methanol.In_(2)O_(3)for CO_(2)hydrogenation to methanol was found by the density functional theoretical study.Thus,In_(2)O_(3)and the supported metal catalysts for CO_(2)hydrogenation are theoretically predictable and excellent model catalysts for studies of single atom catalyst,cluster and nanoparticle catalysts.The conversion route of the In_(2)O_(3)and its supported catalysts is excellent for the definition of catalyst.These catalysts are important for fundamental studies and also for future applications.

关 键 词：氧化铟 催化剂 二氧化碳 加氢 甲醇 

分 类 号：TQ21[化学工程—有机化工] O643.36[理学—物理化学]