酯基取代铜酞菁的合成工艺与性能研究  

Synthesis Technology and Perfromance of Ester Group Substituted Copper Phthalocyanine

作　　者：郭建龙 Guo Jianlong(Small and Medium-sized Enterprise Public Service Center of Duolun,Xilingol League 027300,China)

机构地区：[1]多伦县中小企业公共服务中心,内蒙古锡林郭勒盟027300

出　　处：《山东化工》2023年第1期29-32,共4页Shandong Chemical Industry

摘　　要：以3-硝基邻苯二腈、2,4-二甲基-3-戊醇、氯化铜、N-甲基甲酰苯胺、二茂铁甲酸等为基本原料,经取代、环化、甲酰化、溴代、还原、酯化六步反应合成溴代二羟甲基-四(2,4-二甲基-3-戊氧基)铜酞菁二茂铁甲酸酯化物,以红外光谱跟踪,同时对甲酰化、溴代、还原、酯化反应进行了合成工艺研究,确定了较佳合成条件,并测定了终产物的紫外-可见吸收光谱及在不同溶剂中的溶解性能。Formed from bromine-substituted methylol-tetra(3-amoxy-2,4-dimethyl)phthalocyanine and ferrocenecarboxylic acid as the raw meterials,ester-sustituted phthalocyanine derivative were synthesized by six processes including substitution reaction,cyclization reaction,formylation reaction,bromination reaction,reducion reaction and esterification reaction.Reactions were tracked by infrared spectra.Finally,better conditions were confirmed by the synthesis technologies study of formylation reaction,bromination reaction,reducion reaction,esterification reaction,followed by the determination of the UV-Vis spectrum and solubility of the final product in different solvents as well.

关 键 词：光记录染料 铜酞菁 合成 

分 类 号：TQ596[化学工程—精细化工]