臭氧/双氧水/活性炭深度处理中试工艺效能评估  

Efficiency evaluation of pilot-scale O3/H2O2/Activated carbon advanced treatment process

作　　者：武珉辉 石焱 夏萍 王锋 叶辉 吴洪亮 WU Minhui;SHI Yan;XIA Ping;WANG Feng;YE Hui;WU Hongliang(Shanghai National Engineering Research Center of Urban Water Resources Co.,Ltd.,Shanghai 200082,China;SOLVAY(CHINA)Co.,Ltd.,Shanghai 201108,China)

机构地区：[1]上海城市水资源开发利用国家工程中心有限公司,上海200082 [2]索尔维投资有限公司,上海201108

出　　处：《给水排水》2023年第2期1-7,共7页Water & Wastewater Engineering

基　　金：上海市启明星培育扬帆专项(22YF1412600)。

摘　　要：为评估双氧水在给水厂深度处理改造中的应用潜力,依托中试装置分析了臭氧/双氧水/活性炭工艺中氧化剂投加量和投加比对工艺处理效能的影响,结果表明:与臭氧/活性炭工艺相比,臭氧/双氧水/活性炭工艺对中试装置进水中的COD_(Mn)、土臭素、2-MIB、甲砜霉素和氟甲砜霉素均有更高的去除率,且对于水中富里酸类物质、溶解性微生物代谢产物及自生源组分的削减幅度更大,试验条件下的最优工况为O_(3)投加量1.0 mg/L,O_(3)/H_(2)O_(2)质量比2∶1。在水厂常规的臭氧投加规模下(0.5~1.5 mg/L),臭氧/双氧水/活性炭工艺出水基本没有双氧水残留的问题。In order to evaluate the application potential of H_(2)O_(2)in the advanced treatment of water plant,effects of oxidant dosage and mass ratio on the O_(3)/H_(2)O_(2)/Activated carbon treatment efficiency were analyzed by pilot tests.The results show that compared with O_(3)/Activated carbon treatment process,O3/H_(2)O_(2)/Activated carbon treatment process has a higher removal rate of COD_(Mn),Geosmin,2-MIB,Thiamphenicol and Florfenicol,and the reduction of Fulvic Acid-like,soluble microbial by-product-like and endogenous biological DOM is more efficient.When the O_(3)dosage was 1 mg/L and the O_(3)/H_(2)O_(2)mass ratio was 2∶1,The test reached the optimum condition.Under the conventional ozone dosages of water plant(0.5~1.5 mg/L),there is little need to worry about residue of H_(2)O_(2)in the effluent of O3/H_(2)O_(2)/Activated carbon advanced process.

关 键 词：臭氧/双氧水/活性炭 高级氧化 储备工艺 深度处理 

分 类 号：TU991[建筑科学—市政工程]