纳米纤维素中氢键网络调控技术的研究进展  

Research Progress of Hydrogen Bond Network Regulation Technology of Nanocellulose

作　　者：陈庆辉 朱梦琳 吴朝军[1] 陈业红[1] CHEN Qinghui;ZHU Menglin;WU Chaojun;CHEN Yehong(Qilu University of Technology(Shandong Academy of Sciences)State Key Lab of Bio-based Materials and Green Papermaking,Ji’nan,Shandong Province,250353)

机构地区：[1]齐鲁工业大学(山东省科学院)生物基材料与绿色造纸国家重点实验室,山东济南250353

出　　处：《中国造纸》2023年第3期104-113,共10页China Pulp & Paper

摘　　要：本文讨论了近年来采用衍生化、低共熔溶剂和离子液体处理等技术调控纳米纤维素中氢键网络的研究成果,对比分析了各种技术的调控机理,归纳总结了氢键网络的变化对纳米纤维素结构与性能的影响,简单介绍了分子模拟在氢键断裂与重构研究方面的应用,展望了纳米纤维素氢键网络调控的发展方向。In this paper,the research results of the regulation of hydrogen bonding network of nanocellulose by derivatization,deep eutectic solvent,and ionic liquid treatment in recent years were discussed.The regulatory mechanisms of various techniques were compared and ana‑lyzed,the effects of changes in hydrogen bonding networks on the structure and properties of nanocellulose were summarized.The application of molecular simulation in hydrogen bond breaking and remodeling research was briefly introduced,and the development direction of nanocellulose hydrogen bond network regulation was prospected.

关 键 词：纳米纤维素 氢键网络 构象 调控 分子模拟 

分 类 号：TS712[轻工技术与工程—制浆造纸工程]