烯烃氢甲酰化研究总结与应用  

Research Summary and Application of Olefin Hydroformylation

作　　者：杨旭石 范曼曼 易明武 韩昊 马利群 赖春波 YANG Xushi;FAN Manman;YI Mingwu;HAN Hao;MA Liqun;LAI Chunbo(Wujing Branch of Shanghai Huayi Group Central Research Institute of Chemical Industry Co.,Ltd.,Shanghai 200241,China;Shanghai Coal-Based Polygeneration Engineering Technology Research Center,Shanghai 200241,China;East China University of Science and Technology,Shanghai 200237,China)

机构地区：[1]上海化工研究院有限公司吴泾分公司,上海200241 [2]上海煤基多联产工程技术研究中心,上海200241 [3]华东理工大学,上海200237

出　　处：《肥料与健康》2023年第1期14-18,共5页Fertilizer & Health

基　　金：上海市科学技术委员会项目(22XD1431600);上海煤基多联产工程技术研究中心开放课题(GZKF-MJDLC-04、GZKF-MJDLC-05)。

摘　　要：烯烃氢甲酰化反应是工业上最重要的催化反应之一,作为一种原子经济性反应,符合绿色可持续发展的方向。概述了烯烃氢甲酰化反应催化剂的现有技术;介绍了上海华谊(集团)公司多年来在烯烃氢甲酰化领域有关新型催化剂、反应工艺、关键设备等方面开展的工作,以及在内烯烃、支链烯烃、高选择性合成异构醛等方面进行的基础研究;并对所研究的烯烃氢甲酰化成套技术的国产化和新产品的开发及其前景进行了展望。Olefin hydroformylation is one of the most important catalytic reactions in industry as well as an atomic economy reaction which conforms to the direction of green and sustainable development.The existing technology of olefin hydroformylation catalyst is summarized.The work carried out by Shanghai Huayi(Group)Company in the field of olefin hydroformylation over the years in terms of new catalysts,reaction processes and key equipment,as well as the basic research carried out in the field of internal olefins,branched olefins,and highly selective synthesis of isomeric aldehydes are introduced.The research achievements are promoting future of the localization of olefin hydroformylation complete technology and the development of new products are prospected.

关 键 词：烯烃氢甲酰化 反应动力学 催化剂 反应器 异构醛 

分 类 号：TQ224.4[化学工程—有机化工]