提高海水电解体系中抗氯离子腐蚀性能的研究与策略  

Research and Strategies for Improving Corrosion Resistance of Chloride Ions in Seawater Electrolysis System

作　　者：何娟 周嵬[3] 徐至 He Juan;Zhou Wei;Xu Zhi(School of Chemical Engineering,East China University of Science and Technology,Shanghai 200237,China;School of Chemistry and Chemical Engineering,Huaiyin Normal University,Huaian 223300,China;College of Chemical Engineering,Nanjing Tech University,Nanjing 210009,China)

机构地区：[1]华东理工大学化工学院,上海200237 [2]淮阴师范学院化学化工学院,江苏淮安223300 [3]南京工业大学化工学院,江苏南京210009

出　　处：《稀有金属》2023年第1期105-115,共11页Chinese Journal of Rare Metals

基　　金：国家重点研发计划项目(2021YFB3801301);国家自然科学基金项目(21908054,22075076)资助。

摘　　要：氢能是一种来源丰富、用途广泛和绿色低碳的二次能源,是未来国家能源体系的重要组成部分。可再生资源发电结合电解水制氢工艺体系具备零排放、可循环、可存储和能源互联等特点。其中海水电解制氢工艺不仅解决淡水资源紧缺问题,并且有助于海洋资源的开发与利用。然而,电池阳极的氧析出选择性不高,海水中氯离子以及氯析出产物的腐蚀性强是制约此技术发展的瓶颈问题之一。针对如何提高海水电解制氢体系的抗腐蚀性能与氧析出选择性,本文将从催化剂设计、化学反应体系与工艺设计包含多工艺耦合和反应装置设计等方面,总结前人的研究成果与经验,并提出相应的应对策略和未来发展方向,为后续海水电解制氢技术的研究与应用提供借鉴。Problems such as environmental pollution and lack of fossil energy have always been important issues that have plagued the economic development and people’s lives of all countries in the world.Early,people have paid more attention and production capital to power generation from renewable energy sources such as wind,solar,and tidal energy.However,such natural energy sources are intermittent,random,and fluctuating,and thus cannot be supplied and transmitted continuously.Particularly,the regional problems have resulted in insufficient local power consumption,but long-distance power transmission is difficult and costly.Therefore,the technology and medium that can store and convert electrochemical energy are an urgent need.Hydrogen is a high-energy-density carrier with an energy density of 142 MJ·kg-1,which is not only raw material for chemical production (such as synthetic ammonia) but also an important fuel for hydrogen fuel cells.With the advent of the hydrogen energy ear,the development of the hydrogen economy is expanding day by day.As the core foundation of the hydrogen energy industry chain,hydrogen is rich in sources and widely used,which is a green and low-carbon secondary energy and an important part of the future national energy system.Besides,combined with the electricity generated by renewable resources,the system of producing green hydrogen through water electrolysis has the characteristics of zerocarbon emission,recyclability,storage,and energy interconnection.Nowadays,many mature technologies of water electrolysis for hydrogen production are mostly based on high-purity freshwater resources.The lack of freshwater resources is one of the problems that restrict the large-scale development of such technologies,especially in coastal,central,and western regions where are abundant renewable resources such as wind,solar,and tidal energy.Thus,the electrolytic hydrogen production process using seawater as feed not only solves the shortage of freshwater resources but also contributes to the development and uti

关 键 词：海水电解 氧析出选择性 抗腐蚀性 稳定性 工艺设计 

分 类 号：TK91[动力工程及工程热物理]