1,2,3-三唑类含能化合物的合成研究进展  

Advances in the Synthesis of Energetic Compounds Based on 1,2,3-Triazoles

作　　者：陆祖嘉 秦涧 吴金婷 曹文丽 匡保龙 张建国[1] Lu Zujia;Qin Jian;Wu Jinting;Cao Wenli;Kuang Baolong;Zhang Jianguo(State Key Laboratory of Explosion Science and Technology,Beijing Institute of Technology,Beijing 100081;China North Chemical Research Academy Group Co.LTD.,Beijing 100089;School of Materials Science and Engineering,Southwest University of Science and Technology,Mianyang,Sichuan 621010)

机构地区：[1]北京理工大学爆炸科学与技术国家重点实验室,北京100081 [2]中国北方化学研究院集团有限公司,北京100089 [3]西南科技大学材料科学与工程学院,四川绵阳621010

出　　处：《有机化学》2023年第2期526-554,共29页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.22175025)资助项目。

摘　　要：1,2,3-三唑类含能化合物具有密度高、生成焓高及热稳定性好等特点,近年来受到科研人员的广泛研究和报道.较全面地综述了单环1,2,3-三唑、多环1,2,3-三唑和稠环1,2,3-三唑类含能化合物的研究成果,对其合成方法、感度和爆轰性能进行了总结.结果表明,1,2,3-三唑含能化合物具有良好的爆轰性能和热稳定性,在含能材料领域具有重要的研究价值和应用潜力.最后,对1,2,3-三唑含能化合物的发展现状进行总结与展望,提出了各类1,2,3-三唑含能化合物未来可能的应用方向,以期为从事含能化合物研究的科研人员提供一定的参考.Energetic compounds based on 1,2,3-triazole have the features of high density,high enthalpy of formation and good thermal stability,and these compounds have been extensively studied by researchers in recent years.The latest achievements of energetic compounds based on monocyclic 1,2,3-triazole,polycyclic 1,2,3-triazole and fused ring 1,2,3-triazole are reviewed,and their preparation,sensitivities and detonation performance are also summarized in details.The results show that 1,2,3-triazole compounds have good performance and stability.These compounds show important research value and potential for application in the field of energetic materials.Finally,the development status of 1,2,3-triazole compounds is summarized and prospected,and the possible research directions of various 1,2,3-triazole energetic materials in the future are put forward,in order to provide some reference for researchers engaged in energetic materials.

关 键 词：1 2 3-三唑 含能化合物 合成 感度 爆轰性能 研究进展 

分 类 号：TQ560.1[化学工程—炸药化工]