吸附过程的热力学误差问题的研究  

Study on the Thermodynamic Error Problem of the Adsorption Process

作　　者：聂佳馨 司展 胡晶晶 周华锋[1] NIE Jia-xin;SI Zhan;HU Jing-jing;ZHOU Hua-feng(School of Science,Shenyang University of Chemical Engineering,110142,Shenyang,Liaoning,China;School of Chemical Engineering,Shenyang University of Chemical Engineering,110142,Shenyang,Liaoning,China;School of Computer Science and Engineering,Northeastern University,110819,Shenyang,Liaoning,China)

机构地区：[1]沈阳化工大学理学院,辽宁省沈阳市110142 [2]沈阳化工大学化学工程学院,辽宁省沈阳市110142 [3]东北大学计算机科学与工程学院,辽宁省沈阳市110819

出　　处：《河北水利电力学院学报》2023年第1期50-55,共6页Journal of Hebei University Of Water Resources And Electric Engineering

基　　金：国家自然科学基金青年基金项目(41807350)。

摘　　要：吸附热力学中物理量的误差自上世纪就被学者关注,这种误差被归因于熵焓补偿。对于化学和生物学中类似的物理化学过程,线性焓-熵补偿(EEC)现象是一个热力学谜,长期无法解释。基本的热力学规则并不严格地支持EEC现象,在某些受限条件下,EEC可能呈现出不现实的线性状态。文中将从吸附过程的误差入手,综述对这种误差的解决方式的修正思想与统计力学观点,深入研究熵焓补偿的现象,分析现象产生的原理,认为补偿现象的存在并非数学和量子级别的物理问题。The error of physical quantity in adsorption thermodynamics has been concerned by scholars since the last century,and this error is attributed to the entropy enthalpy compensation.For similar physicochemical processes in chemistry and biology,the linear enthalpy-entropy compensation(EEC)phenomenon is a thermodynamic mystery that cannot be explained for a long time.The basic thermodynamic rules do not strictly support the EEC phenomenon.Under some restricted conditions,the EEC may present an unrealistic linear state.Therefore,In this paper,we start with the error of the adsorption process,review the correction of the solution of this error,and deeply study the phenomenon of entropy enthalpy compensation,analyze the principle of the phenomenon,and think that the existence of the compensation phenomenon is not a mathematical and quantum level physical problem.

关 键 词：熵焓补偿 修正思想 统计力学 量子分析 

分 类 号：P145.8[天文地球—天体物理] O414.1[天文地球—天文学] O413.1[理学—理论物理]