硫化氢干法脱除技术及硫磺回收研究进展  

Research progress of hydrogen sulfide removal technology and sulfur recovery

作　　者：刘振冲 杜昭[1,2,3] 马海彬 LIU Zhen-chong;DU Zhao;MA Hai-bin(School of Environmental Science and Engineering,Hebei University of Science and Technology,Shijiazhuang 050018,China;National Local Joint Engineering Research Center for Volatile Organic Compounds and Odorous Pollution Control Technology,Shijiazhuang 050018,China;Hebei Province Air Pollution Prevention and Control Technology Research and Extension Center,Shijiazhuang 050018,China)

机构地区：[1]河北科技大学环境科学与工程学院,河北石家庄050018 [2]挥发性有机物与恶臭污染防治技术国家地方联合工程研究中心,河北石家庄050018 [3]河北省大气污染防治技术研究推广中心,河北石家庄050018

出　　处：《应用化工》2023年第3期911-916,共6页Applied Chemical Industry

基　　金：河北省重点研发计划项目(19273709D)。

摘　　要：综述了硫化氢干法脱除相关技术,主要包括克劳斯法、碳基吸附、分子筛基吸附、金属氧化物吸附及膜分离技术,重点阐述了硫化氢脱除技术要点及存在问题,详细介绍了干法中硫磺回收工艺的方法类型,包括蒸发冷凝法、溶剂提取、无水液氨浸出、无水乙醇浸出及四氯化碳浸出。指出干法氧化铁脱硫剂应用到转轮技术有巨大潜力,且对于硫磺的回收仍需进行进一步研究。The related technologies of dry removal of hydrogen sulfide are reviewed,including Claus method,carbon-based adsorption,molecular sieve adsorption,metal oxide adsorption and membrane separation,with emphasis on the key points and existing problems of hydrogen sulfide removal technology.The types of sulfur recovery processes in dry process are introduced in detail,including evaporation condensation method,anhydrous liquid ammonia leaching,anhydrous ethanol leaching and carbon tetrachloride leaching.Finally,it is pointed out that dry iron oxide desulfurizer has great potential in rotary wheel adsorption device,and it still has great potential for sulfur recovery.

关 键 词：硫化氢 脱除技术 硫磺回收 

分 类 号：TQ125.1[化学工程—无机化工] X511[环境科学与工程—环境工程] X512