过渡金属活化过硫酸盐降解双酚A的研究进展  

Research progress on degradation of bisphenol A by transition metal activated persulfate

作　　者：张伟 李梅[1,2] 许文[1,2] 丁超民[3] 王文海 白毛毛 ZHANG Wei;LI Mei;XU Wen;DING Chao-min;WANG Wen-hai;BAI Mao-mao(School of Municipal and Environmental Engineering,Shandong Jianzhu University,Jinan 250101,China;Institute of Resources and Environment Innovation,Shandong Jianzhu University,Jinan 250101,China;The Second Construction Limited Company of China Construction Eighth Engineering Division,Jinan 250000,China)

机构地区：[1]山东建筑大学市政与环境工程学院,山东济南250101 [2]山东建筑大学资源与环境创新研究院,山东济南250101 [3]中建八局第二建设有限公司,山东济南250000

出　　处：《应用化工》2023年第3期939-944,954,共7页Applied Chemical Industry

基　　金：山东省自然科学基金项目(ZR2020ME228)。

摘　　要：综述了过渡金属离子、零价金属和双金属等不同类型金属催化剂活化PMS/PDS降解双酚A(BPA)的研究现状;探讨了双金属催化剂活化过硫酸盐去除BPA的降解机理、双金属之间的协同作用以及氧空位与表面羟基的重要作用;分析了活化过程的影响因素、水基质条件,催化剂的可重复使用性与稳定性;对金属催化剂降解BPA研究方向进行了展望。The basic reviewed the research status of different types of metal catalysts,such as transition metal ions,zero-valent metals and bimetals,activated PMS/PDS for the degradation of bisphenol A(BPA),and also discussed the degradation mechanism of BPA removal by bimetallic catalyst.These include synergy between bimetals,and the important role of oxygen vacancies and surface hydroxyl radical.The paper analyzed the influencing factors in the activation process,water matrix conditions,reusability and stability of the catalyst.The paper looks forward to the future research on the degradation of bisphenol A by metal catalysts.

关 键 词：双金属催化剂 过一硫酸盐 过二硫酸盐 高级氧化技术(AOPs) 双酚A(BPA) 

分 类 号：TQ032.4[化学工程] TQ426.8[环境科学与工程—环境工程] X703