金属-有机骨架材料在催化氨硼烷水解释氢中的研究进展  

Recent Advances in Application of Metal-Organic Frameworks for Hydrogen Generation by Catalytic Hydrolysis of Ammonia Borane

作　　者：李冰[1] 刘军辉 宋亚坤[1] 李想[1] 郭旭明[1] 熊健 YU Bing;LIU Jun-Hui;SONG Ya-Kun;LI Xiang;GUO Xu-Ming;XIONG Jian(College of Chemistry and Chemical Engineering,Henan University of Science and Technology,Luoyang 471023,China)

机构地区：[1]河南科技大学化学化工学院,洛阳471023

出　　处：《应用化学》2023年第3期329-340,共12页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金(No.21908043);河南省重点攻关项目(No.222102320314);河南省高等学校重点科研项目(No.22A150011)资助~~

摘　　要：当前,化石燃料的大量消耗和对能源日益增长的需求推动了可再生和高效能源材料的开发。氢因丰富的来源以及清洁的特性而被视为潜在的能源载体。通过水解氨硼烷制备清洁可再生的氢气是解决能源问题的有效途径之一。开发高效安全的催化剂一直是该领域研究的重点和热点。金属-有机骨架材料(MOFs)因其独特的结构、组成和特性,在氨硼烷水解制氢中有广泛的应用。本文以MOFs材料在催化剂设计制备中的作用为侧重点,综述了不同MOFs材料在催化氨硼烷水解制氢反应中的作用,对其在催化氨硼烷水解制氢应用过程中所存在的问题和今后的发展进行了总结和展望。The growing demand for energy is driving the development of renewable and efficient energy materialsdue to the high consumption of fossil fuels.Hydrogen is considered as a potential energy carrier because of its abundant earth sources and clean burning.The preparation of clean and renewable hydrogen by hydrolyzing ammonia borane is one of the effective ways to solve energy problems.The development of efficient and safe catalysts has been the focus and hotspot in this field.Metal-organic framework materials(MOFs)are widely used in ammonia borane hydrolysis for hydrogen production due to their unique structural composition.This paper focuses on the role of MOFs materials in catalyst preparation and summarizes the role of different MOFs materials in catalytic hydrogen production by ammonia borane hydrolysis.In addition,the current problems are summarized and the future development of this field is pointed out.

关 键 词：金属-有机骨架材料 氨硼烷 制氢 催化剂 

分 类 号：O643.3[理学—物理化学]