电感耦合等离子体发射光谱法测定化妆品原料羟丙基四氢吡喃三醇中硼酸盐的残留量  

Residue of Borate in Cosmetics Raw Material Hydroxypropyl Tetrahydropyrantriol Determined by Inductively Coupled Plasma Optical Emission Spectra

作　　者：于海英 李俊婕 牛水蛟 乔振云 胡德福 李启艳 YU Haiying;LI Junjie;NIU Shuijiao;QIAO Zhenyun;HU Defu;LI Qiyan(Shandong Institute for Food and Drug Control/NMPA Key Laboratory for Quality Control of Cosmetics Raw Material,Jinan 250101,Shandong,China;Shandong Meiaohuawei Technology Co.,Ltd.,Jinan 250101,Shandong,China)

机构地区：[1]山东省食品药品检验研究院/国家药监局化妆品原料质量控制重点实验室,山东济南250101 [2]山东梅奥华卫科技股份有限公司,山东济南250101

出　　处：《香料香精化妆品》2023年第2期36-39,58,共5页Flavour Fragrance Cosmetics

基　　金：山东省工业和信息化厅(山东省企业技术创新项目)(编号202150101110)。

摘　　要：建立了一种电感耦合等离子体发射光谱法(ICP-OES)测定化妆品原料羟丙基四氢吡喃三醇中硼酸盐残留量的方法。采用硝酸-过氧化氢-微波消解法进行样品消解,ICP-OES法测定,标准曲线法定量。结果显示,在0.5~20.0μg·mL^(-1)范围内线性关系良好,相关系数为0.9995,回收率在98.3%~100.6%,相对标准偏差(RSD)在1.7%~2.9%,硼酸盐的检出浓度、定量浓度(以硼酸计)分别为0.6、1.8 mg/kg,重复性检测结果的RSD为1.4%(n=6)。该方法操作简单,重复性良好,结果准确,适用于化妆品原料羟丙基四氢吡喃三醇中硼酸盐残留量的测定。A method for determination of borate in cosmetics raw material hydroxypropyl tetrahydropyrantriol was established by inductively coupled plasma optical emission spectra(ICP-OES).Nitric acid and hydrogen peroxide were used as digesting solution,samples were digested by microwave dissolver,detected by ICP-OES,and quantified with the standard curve.The calibration curve had good linearity within 0.5-20μg·mL^(-1) for boron and the correlation coefficient was 0.9995.The recoveries of boron were 98.3%-100.6%.The relative standard deviation(RSD)were 1.7%-2.9%.The limit of detection and the limit of quantitation were 0.6 mg/kg and 1.8 mg/kg for boron(calculated as boric acid),respectively.The relative standard deviation(RSD)of the repeatability result was 1.4%(n=6).The method is simple,accurate,reproducible and suitable for determination of residue of borate in cosmetics raw material hydroxypropyl tetrahydropyrantriol.

关 键 词：化妆品原料 硼酸盐 电感耦合等离子体发射光谱 羟丙基四氢吡喃三醇 

分 类 号：O657.31[理学—分析化学] TQ658[理学—化学]