无乙醇法工业制备的长链烷烃脱氢催化剂性能研究  

RESEARCH ON PERFORMANCE OF LONG-CHAIN ALKANE DEHYDROGENATION CATALYST PREPARED BY ETHANOL-FREE METHOD

作　　者：刘俊[1] 王春生 柯玉剑 盛学虎 Liu Jun;Wang Chunsheng;Ke Yujian;Sheng Xuehu(PetroChina Fushun Petrochemical Company,Fushun,Liaoning 113001)

机构地区：[1]中国石油抚顺石化公司,辽宁抚顺113001

出　　处：《石油炼制与化工》2023年第4期19-23,共5页Petroleum Processing and Petrochemicals

摘　　要：在工业装置上,以水-乙醇为浸渍液溶剂制备长链烷烃脱氢催化剂,考察了溶剂中乙醇的作用。以N_(2)吸附-脱附、X射线衍射、CO脉冲化学吸附、H_(2)-程序升温还原、热重分析等方法对催化剂进行了表征,并在固定床反应器上对催化剂性能进行了评价。结果表明,以无乙醇添加的精制水作浸渍液溶剂制备的长链烷烃脱氢催化剂具有较高的Pt分散性、脱氢活性及较好的活性稳定性。The long-chain alkane dehydrogenation catalyst was prepared with water-ethanol as solvent in an industrial plant,and the effect of ethanol in the solvent was investigated.The catalysts were characterized by N_(2) adsorption-desorption,X-ray diffraction,CO pulse chemisorptions,H_(2)-temperature programmed reduction and thermogravimetric analysis,and the performance of the catalyst was evaluated in a fixed bed reactor.The results showed that the catalysts prepared by ethanol-free solvent impregnation method had high Pt dispersion,dehydrogenation activity and good activity stability.

关 键 词：长链烷烃脱氢 催化剂 浸渍溶剂 乙醇 铂分散性 脱氢性能 

分 类 号：TQ426[化学工程] TQ211