CO_(2)与炔丙醇羧环化合成α-亚烷基环状碳酸酯研究进展  

Research progress on carboxylic cyclization of CO_(2)with propargyl alcohol to synthesize α-alkylidene cyclic carbonate

作　　者：段欣冉 卢雪玉 平冉 董继庆 刘福胜[1] 刘猛帅 DUAN Xinran;LU Xueyu;PING Ran;DONG Jiqing;LIU Fusheng;LIU Mengshuai(State Key Laboratory Base of Eco-chemical Engineering,College of Chemical Engineering,Qingdao University of Science and Technology,Qingdao 266042,China)

机构地区：[1]青岛科技大学化工学院、生态化工国家重点实验室培育基地,山东青岛266042

出　　处：《化工科技》2023年第1期65-73,共9页Science & Technology in Chemical Industry

基　　金：国家自然科学基金项目(22178191);重质油国家重点实验室开放基金项目(SKLHOP202103002)。

摘　　要：CO_(2)是储量丰富、价格低廉、无毒且可再生的C1资源,将CO_(2)转化为高附加值能源及精细化学品是绿色化学的重要研究领域。炔丙醇是有机合成的重要原料,且易于功能化。α-亚烷基环状碳酸酯具有潜在的生物活性,主要应用于药物化学、有机合成等领域。CO_(2)和炔丙醇经羧环化反应制备α-亚烷基环状碳酸酯的过程可实现对CO_(2)的资源化利用,且该反应路线具有原子经济性。围绕CO_(2)与炔丙醇的羧环化反应,系统综述了不同类型催化剂的最新研究进展,为新型催化材料的设计开发指明了方向。CO_(2) is a C1 resource with abundant reserves,low price,non-toxic and recyclable.Converting CO_(2) into high value-added fuels and fine chemical products is one of the major research contents of green chemistry.Propargyl alcohol is an important raw material for organic synthesis,which is easy to be functionalized.α-alkylidene cyclic carbonates have potential biological activities,which are mainly used in pharmaceutical chemistry,organic synthesis and other fields.The process of preparingα-alkylidene cyclic carbonates by carboxylic cyclization of CO_(2) with propargyl alcohols can realize the resource utilization of CO_(2).Meanwhile,the pathway meets the demands of atom economy.In this article,the latest researches with different kinds of catalysts for the carboxylic cyclization of CO_(2) with propargyl alcohol are systematically reviewed,and the direction for the design and synthesis of new catalytic materials is appropriately pointed out.

关 键 词：CO_(2)转化 炔丙醇 α-亚烷基环状碳酸酯 多功能催化剂 

分 类 号：TQ225.52[化学工程—有机化工] TQ426