苯并咪唑内鎓盐金属配合物的合成、晶体结构及性质研究  

Synthesis,Crystal Structures and Properties of Metal Complexes Constructed from Benzimidazolyl Carboxylic Acid

作　　者：张万强 蔡宏芳 邵昶铭 方勇 杨璐 Zhang Wanqiang;Cai Hongfang;Shao Changming;FIang Yong;Yang Lu(Gansu Province Tianshui Ecological and Environmental monitoring Center,Gansu Forestry Polytechnic,Tianshui,Gansu741000,China)

机构地区：[1]甘肃省天水生态环境监测中心、甘肃林业职业技术学院,甘肃天水741000

出　　处：《化学世界》2023年第2期97-103,共7页Chemical World

摘　　要：合成了两种苯并咪唑内嗡盐金属配合物[Ni(dpa)_(2)(H_(2)O)_(4)](1)和[Cu(dpa)_(2)(H_(2)O)_(2)](2)(dpa=2,2-(2-methylbenzimidazolium-1,3-diyl)diacetate),采用X射线衍射表征了配合物1和配合物2的晶体结构。电化学性质表明,金属的配位改变了配体的循环伏安性质。Two two-dimensional supramolecular complexes,[Ni(dpa)_(2)(H_(2)O)_(4)](1)和[Cu(dpa)_(2)(H_(2)O)_(2)](2)(dpa=2,2-(2-methylbenzimidazolium-1,3-diyl)diacetate),have been synthesized.Molecular structures of both complexes were characterized by elemental analysis and single crystal X-ray diffraction.Thermal and electrical properties of both complexes have been investigated.

关 键 词：内鎓盐 晶体结构 热学性质 

分 类 号：O621.148[理学—有机化学]