基于氧杂二甲桥八氢化萘二酐的新型聚酰亚胺共聚物的制备与研究  

Synthesis and research of a series of novel polyimide copolymers derived from dianhydride containing oxa-1,4,4a,5,6,7,8,8a-octahydro-1,4-epoxy-5,8-methanonaphthalene

作　　者：熊磊 熊兵[4] 李双[1] 刘慧 李亮荣 Xiong Lei;Xiong Bing;Li Shuang;Liu Hui;Li Liangrong(School of Pharmacy,Nanchang Medical College,Nanchang 330004;College of Chemistry and Chemical Engineering,Nanchang University,Nanchang 330031;Key Laboratory of Pharmacodynamics and Safety Evaluation,Health Commission of Jiangxi Province,Nanchang 330004;Department of Biochemistry,College of Science and Technology,Nanchang University,Gongqingcheng 332020;Fuzhou Medical College,Nanchang University,Fuzhou 344000)

机构地区：[1]南昌医学院药学院,南昌330004 [2]南昌大学化学化工学院,南昌330031 [3]江西省药效与安全性评价重点实验室,南昌330004 [4]南昌大学科学技术学院生化系,共青城332020 [5]南昌大学抚州医学院,抚州344000

出　　处：《化工新型材料》2023年第3期100-103,共4页New Chemical Materials

基　　金：江西省教育厅科学技术研究项目(GJJ2203521);抚州市科技指导项目(20220906);南昌大学抚州医学院重点科技项目(FYKJ202203)。

摘　　要：通过分子设计合成了一种含氧杂二甲桥八氢化萘大体积结构的新型二酐单体(BADA),并将其按不同的比例与联苯四酸二酐(BPDA)和4,4′-二氨基苯醚(ODA)进行共聚,制备了一系列聚酰亚胺粉末和薄膜材料。通过对新型二酐与新型聚酰亚胺的研究发现,该新型脂环族二酐具有良好的溶解性,且随着脂环族二酐含量的增加,聚酰亚胺表现出优异的溶解性和疏水性,有望应用于5G高频柔性印制电路中。A novel dianhydride monomer(BADA)containing oxa-1,4,4a,5,6,7,8,8a-octahydro-1,4-epoxy-5,8-methanonaphthalene was synthesized by molecular design,and then a series of polyimide copolymers films and powder were prepared by the copolymerization of BADA with diphenyltetracaric anhydride(BPDA)and 4,4′-diaminophenyl ether(ODA)with varying proportions.The results indicated that BADA possessed good solubility,and the polyimide copolymers displayed excellent solubility and hydrophobicity with the increase of the content of BADA.These polyimide copolymers were potential candidates for applications in the fields of 5Ghigh frequency flexible printed circuit.

关 键 词：聚酰亚胺 二酐 脂环族 溶解性 疏水性 

分 类 号：TQ323.7[化学工程—合成树脂塑料工业]