Ligand-induced,magic-size clusters enabled formation of colloidal all-inorganic II-VI nanoplatelets with controllable lateral dimensions  

作　　者：Xufeng Chen Junjun Ge Pengwei Xiao Yalei Deng Yuanyuan Wang 

机构地区：[1]State Key Laboratory of Coordination Chemistry,School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210023,China

出　　处：《Nano Research》2023年第2期3387-3394,共8页纳米研究（英文版）

基　　金：supported by the National Natural Science Foundation of China(No.22171132);the Innovation Fund from Nanjing University(No.020514913419);the Program for Innovative Talents and Entrepreneurs in Jiangsu(Nos.020513006012 and 020513006014).

摘　　要：Achieving nanoconfinement-controlled synthesis of nanoplatelets(NPLs)via solution process under ambient condition remains a challenge.In this work,we developed a general ligand-induced strategy to synthesize colloidal stable all-inorganic semiconductor NPLs with controllable lateral dimensions.By introducing certain metal salts(cations:Zn^(2+)and In^(3+),anions:NO_(3)^(−),BF_(4)^(−),or triflate OTf−),wurtzite-structured(WZ-)CdS,CdSe,CdTe,and alloy Cd1−xZnxSe NPLs were directly synthesized in solution through the controlled diffusion of magic-size clusters(MSCs)at room temperature.Mechanism studies revealed that destabilization of MSCs and nanoconfined growth in templates facilitated the formation of NPLs.The present study not only provides a new synthetic route for the preparation of NPLs but also helps to provide insight into their probable formation mechanism and presents an important advance toward the rational design of functional nanomaterials.

关 键 词：magic-size cluster NANOPLATELETS all-inorganic lateral dimensions controlled inorganic ligands 

分 类 号：O61[理学—无机化学]