半经验模型对分散橙25在超临界CO_(2)中溶解度的拟合  

Correlation of the solubility of disperse orange 25 by semi-empirical model in supercritical carbon dioxide

作　　者：杜慧 闫俊[1] 李红[1] 张欢[1] 方帅军[2] DU Hui;YAN Jun;LI Hong;ZHANG Huan;FANG Shuaijun(Liaoning Provincial Key Laboratory of Supercritical CO2 Dyeing,Dalian Polytechnic University,Dalian 116034,Liaoning,China;College of Textile and Garment,Shaoxing University,Shaoxing 312000,Zhejiang,China)

机构地区：[1]大连工业大学辽宁省超临界二氧化碳无水染色重点实验室,辽宁大连116034 [2]绍兴文理学院纺织服装学院,浙江绍兴312000

出　　处：《东华大学学报（自然科学版）》2023年第2期144-149,共6页Journal of Donghua University(Natural Science)

基　　金：生态纺织教育部重点实验室(江南大学)开放课题(KLET1808);浙江省清洁染整技术研究重点实验室开放课题(QJRZ1915);2019年教育部春晖计划;大连市青年科技之星(2018RQ26)。

摘　　要：为获得最佳的溶解度试验数据并得到溶解度与工艺测量条件之间的关系,探究分散染料在超临界CO_(2)流体中的溶解规律。在温度343.15~393.15 K、压力10~22 MPa的条件下,使用超临界流体试验装置测量分散橙25在超临界CO_(2)流体中的溶解度,并对染料的溶解性进行分析。利用Kumar-Johnston(K-J)、Sung-Shim(SS)和Mendez-Santiago-Teja(MST)等3种半经验模型对染料的溶解度进行拟合。结果表明:染料的溶解度随压力和温度的升高而增加;K-J、SS和MST模型的平均相对偏差分别为7.55%、8.20%和11.92%,其中K-J模型拟合下的试验值和计算值的相关性最高,关联效果优于其他两种半经验模型。To obtain the best solubility experimental data and the relationship between solubility and measurement conditions,the solubility of disperse dyes in supercritical CO_(2)fluid was investigated.The solubility of disperse orange 25 in supercritical CO_(2)fluid was measured using a supercritical fluid test apparatus under the conditions of temperature 343.15 K to 393.15 K and pressure 10 MPa to 22 MPa,and the solubility of the dye was analyzed.Three semi-empirical models,Kumar-Johnston(K-J),Sung-Shim(SS)and Mendez-Santiago-Teja(MST),were used to fit the solubility of the dye.The results show that the solubility increases with the increase of pressure and temperature;the average absolute relative deviation of the three models of K-J,SS and MST is 7.55%,8.20%and 11.92%,respectively.The correlation between experimental values and calculated values under K-J model is the highest,and the correlation effect is better than that of the other two semi-empirical models.

关 键 词：溶解度 超临界CO_(2) 分散橙25 半经验模型 

分 类 号：TS193.1[轻工技术与工程—纺织化学与染整工程]