金属有机铂(Ⅱ)配合物在光限幅材料中的研究进展  

Research advances in organometallic Pt(Ⅱ)complexes in optical power limiting materials

作　　者：胡来 淦三鹏 朱红军 朱森强 刘睿 HU Lai;GAN Sanpeng;ZHU Hongjun;ZHU Senqiang;LIU Rui(School of Chemistry and Molecular Engineering,Nanjing Tech University,Nanjing 211816,China)

机构地区：[1]南京工业大学化学与分子工程学院,南京211816

出　　处：《有色金属材料与工程》2023年第2期1-10,共10页Nonferrous Metal Materials and Engineering

基　　金：江苏省自然科学基金资助项目(BK20220351);江苏省高校自然科学研究面上项目(22KJB150027)。

摘　　要：随着激光技术不断发展并走向成熟,如何防止激光损伤已经成为亟待解决的科学问题。铂(Ⅱ)配合物因其结构稳定、光物理性质丰富、化学修饰性及光谱可调性强,以及激发态寿命长等特点,在光限幅材料领域中被广泛应用。当前,开发限幅性能优异、光学窗口宽且透光性高的铂(Ⅱ)配合物光限幅材料成为激光防护领域中的研究热点。重点介绍了近年来报道的各类铂(Ⅱ)配合物的光物理性质调控和光限幅性能研究,并对该领域的发展趋势进行了展望,以期为开发新型铂(Ⅱ)配合物光限幅材料提供一定的参考。With the continuous development and maturation of laser technology,preventing the laser damage has become an urgent scientific problem.Pt(Ⅱ)complexes have been widely used in optical power limiting materials because of their structural stability,rich photophysical properties,chemical modifiability and spectral tunability,and long excited state lifetimes.For now,developing optical power limiting materials with excellent limiting performance,broad optical windows,and high transmittance of Pt(Ⅱ)complexes has become a hot research topic in the field of laser protection.This review highlights the photophysical property modulation and optical power limiting performance of various types of Pt(Ⅱ)complexes reported in recent years and provides an outlook on the development trend in this field,to provide some guidences for the development of novel Pt(Ⅱ)complexes optical limiting materials.

关 键 词：铂 激光防护 配合物 光物理性质 光限幅 

分 类 号：TN244[电子电信—物理电子学]