Design and Synthesis of Al_(7)Ni_(2) Heterometallic Clusters Based on Metal Substitution and Ligands Protection Strategies  

作　　者：Ya-Jie Liu Li-Min Cui Wei-Hui Fang Jian Zhang 

机构地区：[1]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China [2]University of Chinese Academy of Sciences,Beijing 100049,China

出　　处：《Chinese Journal of Chemistry》2023年第5期521-526,共6页中国化学（英文版）

基　　金：This work is supported by the National Natural Science Foundation of China(92061104,21935010 and 21973096);the Natural Science Foundation of Fujian Province(2021J06035);the Youth Innovation Promotion Association CAS(Y2018081).

摘　　要：The synthesis of heterometallic aluminum-based materials is challenging yet attractive,due to their potential applications in optics,catalysis,magnetism and semiconductor device.We have now successfully synthesized two Al,Niz heterometallic clusters bearing different peripheral alkoxide ligands through a heterometal substitution strategy.

关 键 词：Cluster compounds Heterometallic complexes Crystal engineering Catalytic properties Aluminum oxo cluster ALUMINUM 

分 类 号：O62[理学—有机化学]