Nucleophilic Radicals as Hydrogen Atom Abstractors in C(sp3)-H Functionalization Reactions  

作　　者：Tao Li Jian Li Haohua Huo 

机构地区：[1]State Key Laboratory of Physical Chemistry of Solid Surfaces,Key Laboratory of Chemical Biology of Fujian Province,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China

出　　处：《Chinese Journal of Chemistry》2023年第5期544-547,共4页中国化学（英文版）

基　　金：We are grateful for financial support from the National Key R&D Program of China(2021YFA1502500);National Natural Science Foundation of China(22071203);Fundamental Research Funds for the Central Universities(20720210014).

摘　　要：Hydrogen atom transfer(HAT)is an elementary mechanistic step in organic synthesis.The photoredox-catalyzed HAT has transformed organic synthesis by enabling the activation and subsequent cross-coupling of traditionally inert yet ubiquitous C(sp^(3))-H bonds.

关 键 词：RADICALS Hydrogen atom transfer(HAT) C(sp^(3))-H functionalization Polarity matching Photocatalysis 

分 类 号：O62[理学—有机化学]