疏水型共价有机框架的合成及应用研究进展  

Progress on the synthesis and application of hydrophobic covalent organic frameworks

作　　者：李秋爽 赵冰[1,2] 阚伟[1,2] 王丽艳[1,2] 王秀文 Li Qiushuang;Zhao Bing;Kan Wei;Wang Liyan;Wang Xiuwen(College of Chemistry and Chemical Engineering,Qiqihar University,Qiqihar 161001;Heilongjiang Provincial Key Laboratory of Surfactants and Industrial Additives,Qiqihar University,Qiqihar 161001)

机构地区：[1]齐齐哈尔大学化学与化学工程学院,齐齐哈尔161001 [2]齐齐哈尔大学黑龙江省表面活性剂与工业助剂重点实验室,齐齐哈尔161001

出　　处：《化工新型材料》2023年第4期14-19,共6页New Chemical Materials

基　　金：国家自然科学基金(21978140);黑龙江省自然科学基金项目(GZ20210064);黑龙江省省属本科高校基本科研业务费科研项目(135309116)。

摘　　要：共价有机框架(COFs)是一种新兴的晶体多孔聚合物,因其组成多样化、孔径可调、高稳定性等优点已在很多领域表现出优异的应用前景。随着疏水材料的不断发展,疏水型COFs材料备受关注,其结构类型的设计、开发及应用研究已有相关报道。鉴于此,从C(主要包括含氟类、长链烷烃类及其他芳香烃类疏水型COFs材料)及合成策略方面综述了近年来疏水型共价有机框架相关研究进展。此外,简要介绍了疏水型COFs材料在油水分离、固相微萃取与吸附领域的应用。Covalent organic frameworks(COFs),as an emerging crystal porous polymer,have exhibited excellent application prospects in various fields because of its advantages of abundant constitution,controllable aperture,high stability and so on.With the continuous development of hydrophobic materials,hydrophobic COFs materials have been paid much attention.More recently,the corresponding research about the structural designation and synthesis,as well as the application have been reported widely.In view of these,the recent progress on hydrophobic COFs materials was reviewed in this paper,mainly including the classification(such as fluorine-containing,long chain alkyl groups,and aromatic hydrocarbon) and the synthetic strategy.In addition,its application in the fields of the oil/water separation,the solid phase microextraction and adsorption were also introduced briefly.

关 键 词：共价有机框架 疏水型 分类 合成策略 应用 

分 类 号：TB332[一般工业技术—材料科学与工程]