基于碳纳米管的光伏电池  

Photovoltaic Cells Based on Carbon Nanotubes

作　　者：王龙 周庆萍 吴钊峰 张延铭 叶小我 陈长鑫 Long Wang;Qingping Zhou;Zhaofeng Wu;Yanming Zhang;Xiaowo Ye;Changxin Chen(School of Physics Science and Technology,Xinjiang University,Urumqi 830046,China;National Key Laboratory of Science and Technology on Micro/Nano Fabrication,Key Laboratory for Thin Film Fabrication of the Ministry of Education,Department of Micro/Nano Electronics,School of Electronic Information and Electrical Engineering,Shanghai Jiao Tong University,Shanghai 200240,China)

机构地区：[1]新疆大学物理科学与技术学院,乌鲁木齐830046 [2]上海交通大学电子信息与电气工程学院微纳电子学系,微米/纳米加工技术国家级重点实验室,薄膜与微细技术教育部重点实验室,上海200240

出　　处：《化学进展》2023年第3期421-432,共12页Progress in Chemistry

基　　金：国家自然科学优秀青年科学基金项目(No.61622404);国家自然科学基金面上项目(No.62074098);教育部长江学者奖励计划青年学者项目(No.Q2017081);浙江福莱新材料股份有限公司项目资助。

摘　　要：碳纳米管具有独特的一维结构和优异的光电特性,是构建光伏电池的理想材料。本文主要综述了近年来碳纳米管基光伏电池的结构设计、制备方法以及碳纳米管在器件中的不同功能应用。首先概述了碳纳米管的结构和光电特性,重点讨论了碳纳米管作为光电转换材料、导电电极和载流子传输层等功能层时器件的原理、制作方法及优缺点,介绍了碳纳米管在微型光伏电池、碳纳米管/硅异质结光伏电池、染料敏化光伏电池、钙钛矿光伏电池、有机光伏电池以及柔性光伏电池中的应用,最后总结了碳纳米管基光伏电池的优势和挑战,以期为新型碳基光伏电池的设计和制作提供思路和参考。Carbon nanotubes(CNTs)are ideal materials for building photovoltaic cells due to their unique one-dimensional structure and excellent photoelectric properties.In this paper,we review recent structural design,fabrication method and device performance of CNT-based photovoltaic cells and different functional roles of CNTs in these devices.Firstly,the structure and photoelectric properties of CNTs are introduced.Then,we emphatically discuss the operation principles,the fabrication methods and the advantages and shortage of the photovoltaic cells with CNTs used as the photoelectric conversion materials,conducting electrodes and carrier transport layers in the devices.The applications of carbon nanotubes in Micro photovoltaic cell,carbon nanotube/silicon heterojunction photovoltaic cells,dye sensitized photovoltaic cells,perovskite photovoltaic cells,organic photovoltaic cells and flexible photovoltaic cells are introduced.Finally,the advantages and challenges of CNT-based photovoltaic cells are summarized.This paper will provide new idea and reference for the design and fabrication of novel carbon-based photovoltaic cells.

关 键 词：碳纳米管 光伏电池 光电转换 功率转换效率 透明导电电极 

分 类 号：TM914.4[电气工程—电力电子与电力传动]