MOFs材料的合成及其烷烃异构化研究进展  

Progress in Synthesis and Alkane Isomerization of MOFs

作　　者：郭强[1] 马守涛[1,2] 崔艳红 姜震 张微[1] 刘金艳[1] 林文秋 所艳华 汪颖军[1] GUO Qiang;MA Shoutao;CUI Yanhong;JIANG Zhen;ZHANG Wei;LIU Jinyan;LIN Wenqiu;SUO Yanhua;WANG Yingjun(College of Chemistry and Chemical Engineering,Northeast Petroleum University,Daqing 163318,China;Daqing Petrochemical Research Center,Petrochemical Research Institute of PetroChina,Daqing 163714,China;Inspection and Test Center of Agricultural and Processed Products(Daqing),Ministry of Agriculture and Rural Affairs,Test Center of Heilongjiang Bayi Agricultural University/Quality Supervision,Daqing 163000,China)

机构地区：[1]东北石油大学化学化工学院,黑龙江大庆163318 [2]中国石油石油化工研究院大庆化工研究中心,黑龙江大庆163714 [3]黑龙江八一农垦大学测试中心,农业农村部农产品及加工品质量监督检验测试中心,黑龙江大庆163000

出　　处：《化学与粘合》2023年第3期253-257,269,共6页Chemistry and Adhesion

基　　金：东北石油大学“国家基金培育”基金(编号:2017PYYL03);东北石油大学化学工程与技术优势特色学科青年学术骨干支持计划资助项目;黑龙江省自然科学基金联合引导项目(编号:LH2019B025)。

摘　　要：金属有机框架材料(MOFs)是一种具有三维空间结构的新型多孔材料。由于其卓越的理化性能,使MOFs在吸附分离、多相催化、电催化和生物医药等众多领域都有非常出色的表现。因其具有超高的比表面积、可调节的孔道结构、数量众多的活性位点和化学组成可调等优点,所以成为了备受关注的催化材料之一。烷烃异构化是一种可以显著地提高汽油的辛烷值和品质的技术,异构化汽油燃烧后污染物的排放量有着明显的降低,符合可持续发展的要求。同时,异构化烷烃也可以作为原材料制备一些重要的化工材料。主要介绍了MOFs材料的类型和常用的合成方法,综述了其在烷烃异构化领域的应用现状及表征方法,并对其在烷烃异构化领域的应用前景进行了展望。Metal-organic frameworks(MOFs)are new porous materials with three dimensions structures.MOFs shows excellent performance in many fields such as adsorption separation,multiphase catalysis,electrocatalysis and biomedicine.Because of their remarkable physical and chemical properties including high surface area,adjustable pore structure,a large number of active sites and adjustable chemical composition,the MOFs have become one of the most popular catalyst materials.The alkane isomerization reaction can not only significantly improve the octane number of gasoline as well as improve the quality of gasoline,but also can reduce the emission of pollutants after gasoline combustion,which meets the requirements of sustainable development.Some other chemical raw materials can also be prepared by this technology.Several common synthesis methods for preparing MOF materials are introduced,and the application prospect of MOFs in alkane isomerization reaction is presented.

关 键 词：金属有机框架材料 烷烃异构化 合成方法 催化剂 

分 类 号：O643.3[理学—物理化学]