Piezoelectrically Mediated Reactions:From Catalytic Reactions to Organic Transformations  

作　　者：Ziye Ren Yuhao Peng Hanliang He Chengqiang Ding Jialin Wang Zhao Wang Zhengbiao Zhang 

机构地区：[1]State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials,Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application,Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis,College of Chemistry,Chemical Engineering and Materials Science,Soochow University,Suzhou,Jiangsu 215123,China [2]Suzhou Medical College,Soochow University,Suzhou,Jiangsu 215123,China [3]The Department of Orthopedic Surgery,Dushu Lake Hospital Affiliated to Soochow University,Suzhou,Jiangsu 215123,China [4]State Key Laboratory of Radiation Medicine and Protection,Soochow University,Suzhou,Jiangsu 215123,China

出　　处：《Chinese Journal of Chemistry》2023年第1期111-128,共18页中国化学（英文版）

基　　金：supported by the National Natural Science Foundation of China(22101195 and 21925107);the Natural Science Foundation of liangsu Province(BK20210732);the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD);the Program of Innovative Research Team of Soochow University;We thank Dr.Bo Tang for the helpful discussion and support from the Special Key Project of Technology Innovation and Application Development of Chongqing(No.cstc2020jscx-dxwtBx0025).

摘　　要：Recently,piezocatalysis has attracted considerable attention as a new type of renewable mechanical energy conversion technology,which relies on the strain induced polarization of the piezoelectric material.This new technology has been extensively applied in the applications of water splitting,water remediation,gas purification and tumor therapy.Despite the rapid development in the piezo-catalysis,the utilization of piezoelectric materials for synthetic purpose is still under exploration.Piezoelectric means to promote or-ganic reactions expand the scope of piezoelectrically mediated reactions and show successes in both organic and polymer synthesis.Herein,we provide a comprehensive review on recent progress of piezoelectrically mediated reactions,catalytic mechanisms and applications in the last few years.The limitations and future directions of this area are also discussed.We believe this review will provide new insights into the underlying mechanism of piezoelectric mediated electron transfer process and guide the design of new chemistry.

关 键 词：Piezocatalysis Heterogeneous catalysis Mechanical energy POLYMERIZATION Organic synthesis Water spilling Tumor therapy Mechanoredox Piezoelectric material 

分 类 号：O64[理学—物理化学]