烯烃烷氧羰基化反应研究进展  

Research progress on alkoxycarbonylation of alkenes

作　　者：黄承杰 刘品涵 范立海 郑辉东 吴丹 Huan Chengjie;Liu Pinhan;Fan Lihai;Zheng Huidong;Wu Dan(College of Chemical Engineering,Fuzhou University,Fuzhou 350116,Fujian,China;Qingyuan Innovation Laboratory,Quanzhou 362801,Fujian,China)

机构地区：[1]福州大学石油化工学院,福建福州350116 [2]清源创新实验室,福建泉州362801

出　　处：《工业催化》2023年第5期1-11,共11页Industrial Catalysis

基　　金：国家自然科学基金项目(21506035,22078065);泉州市引进高层次人才团队项目(2021CT006)。

摘　　要：烯烃的烷氧羰基化反应是目前生产酯类化合物最重要的均相催化反应,烷氧羰基化反应催化剂的开发与改性备受关注。此外,均相烷氧羰基化催化剂的回收和无“CO”的羰基化过程也一直是烷氧羰基化反应的研究热点。综述近年来烷氧羰基化反应催化剂的研究进展,归纳双膦配体上不同活性基团对催化剂性能的影响,总结均相烷氧羰基化催化剂的固载化和液-液两相体系两种催化剂的回收方法,介绍甲酸、甲醛和CO_(2)三种羰基源替代物实现烯烃高效羰基化的反应方法。Alkoxycarbonylation of alkenes is one of the most important homogeneous reactions for the industrial production of esters.And the development or the modification of its catalyst has been paid extensive attention.Furthermore,the recovery of homogeneous catalysts and“CO-free”carbonylation have been the research focus of alkoxycarbonylation.In this paper,the research progress on alkoxycarbonylation catalysts in recent years was reviewed,and the effects of the different active groups in bisphosphine ligands on the alkoxycarbonylation activity of the catalyst were summarized.Moreover,the immobilized homogeneous alkoxycarbonylation catalysts and the liquid-liquid biphasic systems were introduced for the catalyst recovery,and the efficient carbonylation of alkenes with three carbonyl substituents of formic acid,formaldehyde and CO_(2)was discussed,respectively.

关 键 词：精细化学工程 烷氧羰基化反应 均相催化剂 固载化 配合物 一氧化碳 

分 类 号：TQ426.94[化学工程] TQ225.24