绿豆中螺螨酯残留的HPLC/MS/MS法检测及其膳食摄入风险评估  

Determination of Spirodiclofen Residue in Mungbean and Plant by HPLC-MS/MS and Dietary Intake Risk Assessment

作　　者：臧娅磊 李萌 吴绪金 张可松 郑先福[3] Zang Yalei;Zhang Kesong;Li Meng;Wu Xujin;Zheng Xianfu(Zhengzhou Zheng Shi Chemical Co.,Ltd./Henan Crop Chemical Control Engineering Research Center,Zhengzhou Henan 450002,China;Institute of Quality Standard and Testing Technology for Agro-products,Henan Academy of Agricultural Sciences,Zhengzhou Henan 450002,China;Henan Agricultural University,Zhengzhou Henan 450000,China)

机构地区：[1]郑州郑氏化工产品有限公司/河南省作物化控工程技术研究中心,河南郑州450002 [2]河南省农业科学院农业质量标准与检测技术研究所,河南郑州450002 [3]河南农业大学,河南郑州450000

出　　处：《农药科学与管理》2023年第4期37-43,64,共8页Pesticide Science and Administration

摘　　要：建立了螺螨酯在绿豆和植株中残留的HPLC/MS/MS法检测方法,并对绿豆中螺螨酯残留量进行了膳食摄入风险评估。方法平均回收率分别为87%~105%和81%~86%,相对标准偏差分别为6.8%~7.1%和6.4%~7.3%。绿豆和植株中螺螨酯的最低检测浓度均为0.01 mg/kg。按本试验设计进行施药,不同采收间隔期绿豆和植株中螺螨酯的残留量分别为≤0.055 mg/kg和≤3.6 mg/kg。螺螨酯的普通人群国家估计每日摄入量是0.0031 mg,占日允许摄入量的0.5%左右,认为对一般人群健康不会产生不可接受的风险。The analytical method for the residues of spirodiclofen in mungbean and plant was established by HPLC/MS/MS,and the risk assessment for dietary intake of mungbean was evaluated.The average recoveries of spirodiclofen in mungbean and plant were shown to range from 87 to 105 percent and 81 to 86 percent,respectively,with a relative standard deviation(RSD)of 6.8%to 7.1%and 6.4%to 7.3%,respectively.The limits of quantification(LOQ)were 0.01 mg/kg for both mungbean and plant detection.The terminal residues of spirodiclofen under different PHI in mungbean and plant were lower than 0.055 mg/kg and 3.6 mg/kg,respectively.The international estimated daily intake(IEDI)of spirodiclofen was 0.0031 mg,accounting 0.5%of ADI,which demonstrated that spirodiclofen will not cause an unacceptable potential health risk for the general public.

关 键 词：螺螨酯 绿豆 残留检测 膳食摄入评估 

分 类 号：S482.52[农业科学—农药学] S481.8[农业科学—植物保护]