介绍一个综合实验:利用Briggs-Rauscher振荡体系检测对羟基苯乙酮  

Introduce a Comprehensive Experiment:Determination of P-Hydroxyacetophenone by Using a Briggs-Rauscher Oscillating Reaction

作　　者：王俊[1] 李白 陈卓 潘亚男 胡刚[1] Wang Jun;Li Bai;Chen Zhuo;Pan Yanan;Hu Gang(College of Chemistry and Chemical Engineering,Anhui University,Hefei 230601,China)

机构地区：[1]安徽大学化学化工学院,安徽合肥230601

出　　处：《山东化工》2023年第6期123-125,130,共4页Shandong Chemical Industry

基　　金：国家自然科学基金项目(21171002);安徽大学化学化工学院教研项目专项基金(2020-9)。

摘　　要：介绍了一个综合实验,在合成四氮杂大环配合物[NiL](ClO_(4))_(2)基础上,构建一个以四氮杂大环配合物[NiL](ClO_(4))_(2)催化的Briggs-Rauscher非线性化学振荡体系,并用此体系来实现对对羟基苯乙酮的定量检测。其中,配合物[NiL](ClO_(4))_(2)中的配体L为5,7,7,12,14,14-六甲基-1,4,8,11-四氮杂环十四烷-4,11-二烯。该综合实验囊括了无机化学,分析化学,有机化学,物理化学的有关知识,使用数字化仪器和电脑软件,使得操作简便,结果精确。A comprehensive experiment is introduced in this paper.Based on the synthesis of[NiL](ClO_(4))_(2),a Briggs-Rauscher chemical oscillation system using[NiL](ClO_(4))_(2) as catalyst was studied,and Briggs-Rauscher system was used for quantitative detection of p-hydroxyacetophenone.The L in the complex is 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene.This comprehensive experiment includes inorganic chemistry,analytical chemistry,organic chemistry,physical chemistry.The digital instruments and computer software were used in comprehensive experiment,making the operation simple,results accurate.

关 键 词：Briggs-Rauscher 振荡反应 合成 分析测定 综合化学实验 

分 类 号：O6-33[理学—化学]