Conversion reaction lithium metal batteries  

作　　者：Wenbo Lu Zhaopeng Li Huaifang Shang Lifang Jiao 

机构地区：[1]Key Laboratory of Magnetic Molecules and Magnetic Information Materials(Ministry of Education),School of Chemistry and Material Science,Shanxi Normal University,Taiyuan 030031,China [2]Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education),Renewable Energy Conversion and Storage Center(ReCast),College of Chemistry,Nankai University,Tianjin 300071,China

出　　处：《Nano Research》2023年第6期8219-8252,共34页纳米研究（英文版）

基　　金：supported by the National Natural Science Foundation of China(Nos.52025013,52071184,52171228,21705103,and 52202266);the Natural Science Foundation of Tianjin(No.22JCZDJC00170);the 111 Project(No.B12015);the Fundamental Research Funds for the Central Universities,the Applied Basic Research Project of Shanxi Province(Nos.202103021224251 and 202103021223259).

摘　　要：Contemporary social problems,such as energy shortage and environmental pollution,require developing green energy storage technologies in the context of sustainable development.With the application of secondary battery technology becoming widespread,the development of traditional lithium(Li)-ion batteries,which are based on insertion/deinsertion reactions,has hit a bottleneck;instead,conversion-type lithium metal batteries(LMBs)have attracted considerable attention owing to the high theoretical capacity of Li metal anodes.In this review,Li-S,Li-O_(2),and Li-SOCl_(2)batteries are used as examples to summarize LMBs based on their conversion reactions from the perspectives of cathode material,anode material,electrolyte,separator,and current collector.Key challenges exist regarding the conversion reactions of various batteries.To achieve the optimum performance and improve the application effect,several improvement strategies have been proposed in relation to reasonable designs of next-generation high-performance rechargeable batteries.

关 键 词：lithium(Li)metal batteries conversion reaction lithium-sulfur battery lithium-oxygen battery lithium-SOCl_(2)battery 

分 类 号：TM912[电气工程—电力电子与电力传动]