多功能性聚苯并噁嗪树脂及其纳米复合材料研究进展  

Research Progress of Multifunctional Polybenzoxazine Resin and Its Nanocomposites

作　　者：赵威 蒋冰 李鑫康 倪可扬 魏聪 蔺海兰[1] 卞军[1] 陈代强[2] 常凯军 蔡旭光 Zhao Wei;Jiang Bing;Li Xinkang;Ni Keyang;Wei Cong;Lin Hailan;Bian Jun;Chen Daiqiang;Chang Kaijun;Cai Xuguang(School of Materials Science and Engineering,Xihua University,Chengdu 610039,China;College of Polymer Science and Engineering,Sichuan University,Chengdu 610065,China;Hainan Guzun Technology Co.,Ltd.,Haikou 570100,China;Changzhou Yuanran New Material Technology Co.,Ltd.,Changzhou 213000,China)

机构地区：[1]西华大学材料科学与工程学院,成都610039 [2]四川大学高分子科学与工程学院,成都610065 [3]海南古樽科技有限公司,海口570100 [4]常州源自然新材料科技有限公司,江苏常州213000

出　　处：《工程塑料应用》2023年第5期159-164,共6页Engineering Plastics Application

基　　金：国家教育部春晖计划合作项目(Z2023-XXX,Z2018088);西华大学Interface创新研究工作室重点建设项目;西华大学西华杯大学生创新创业训练项目(S2023106500-XX);西华大学研究生创新基金项目(SA2000002910)。

摘　　要：简要介绍了聚苯并噁嗪树脂(PBZ)作为新型酚醛型热固性树脂的性能及其应用,并指出了目前存在的不足。对PBZ树脂的合成方法及优缺点进行了概述,并对其开环机理及功能化改性进行了补充。在此基础上,回顾了PBZ复合材料目前国内外共聚、共混两大体系的研究现状,分析了在不同结构和方法下PBZ的性能。针对PBZ基纳米复合材料,分为碳基纳米材料和非碳基纳米材料两类,并对其作了较为详尽的综述。最后对PBZ树脂及其复合材料的发展前景与应用前景作了展望。The properties of polybenzoxazine resin(PBZ)as a new phenolic-type thermosetting resin and its applications were briefly described and the current deficiencies were pointed out.Subsequently,the synthesis methods and advantages and disadvantages of PBZ resins were outlined,and their ring-opening mechanisms and functionalized modifications were supplemented.On this basis,the current research status of PBZ composites in two major systems,copolymerization and blending,at home and abroad was reviewed,and the effects on PBZ properties under different structures and methods were analyzed.For PBZ-based nanocomposites,they are divided into two categories:carbon-based nanomaterials and non-carbon-based nanomaterials,and a more detailed review was given.Finally,the prospects for the development and application of PBZ resins and their composites were presented.

关 键 词：聚苯并噁嗪树脂 复合材料 力学性能 热学性能 研究进展 

分 类 号：TQ325[化学工程—合成树脂塑料工业]