氨基纤维素功能材料的合成与应用  

Progresses on the Synthesis of Aminocellulose and Its Functional Materials

作　　者：贾家海 陈铭杰 施庆珊 谢小保 李海明 王兴 周景蓬[3] 刘燕韶[3] 张凤山[3] 郭延柱 Jiahai Jia;Mingjie Chen;Qingshan Shi;Xiaobao Xie;Haiming Li;Xing Wang;Jingpeng Zhou;Yanshao Liu;Fengshan Zhang;Yanzhu Guo(Liaoning Key Laboratory of Biomass Chemistry and Material,Liaoning Lignofiber Biomass Refining Collaborative Innovation Center,College of Light Industry and Chemical Engineering,Dalian Polytechnic University,Dalian 116034,China;Guangdong Provincial Key Laboratory of Microbial Culture Collection and Application,State Key Laboratory of Applied Microbiology Southern China,Institute of Microbiology,Guangdong Academy of Sciences,Guangzhou 510070,China;Huatai Group Co.LTD,Dongying 257335,China)

机构地区：[1]大连工业大学轻工与化学工程学院辽宁省生物质化学与材料重点实验室辽宁木质纤维生物质精炼协同创新中心,辽宁大连116034 [2]广东省科学院微生物研究所华南应用微生物国家重点实验室广东省菌种保藏与应用重点实验室,广东广州510070 [3]华泰集团有限公司,山东东营257335

出　　处：《高分子材料科学与工程》2023年第4期163-172,共10页Polymer Materials Science & Engineering

基　　金：国家自然科学基金面上项目(22078036);中国博士后科学基金第69批面上项目(2021M691106);山东省博士后创新项目;广东省科学院发展专项资金项目(2022GDASZH-2022010101);广东省科技厅项目(2021QN02C793)。

摘　　要：氨基化改性可有效地破坏纤维素固有的结晶结构,赋予纤维素一定的碱性,改善纤维素的水溶性,极大地提升了纤维素的利用价值。文中对氨基纤维素的合成路径及结构特征进行了归纳总结。通过具体实例分析,总结了氨基纤维素在吸附、生物医药、催化剂和酶蛋白固载领域的应用,提出了氨基纤维素绿色合成、生物相容性分析、仿生材料设计等研究发展方向。期望为氨基纤维素的利用提供理论参考,为氨基纤维素的研究提供方向。Amination modification can effectively destroy the inherent crystalline structure of cellulose,impart excellent water solubility and alkalinity to aminocellulose,and thus improve the utilization value of cellulose.In order to guide the synthesis and utilization of aminocellulose,the synthetic pathway and structural characteristics of aminocellulose were reviewed in this paper.In addition,the applications of aminocellulose in the fields of adsorption,biomedicine,catalysts,and enzyme protein fixation were discussed on the basis of concrete examples.It is prospected that the green preparation of aminocellulose,and its biocompatibility analysis with the aim of fabricating biomimetic material will be the future focuses.The discussion of this paper would show light on the synthesis and utilization of aminocellulose.

关 键 词：纤维素 氨基 改性 合成 功能材料 

分 类 号：TQ352.7[化学工程]