金属基催化剂催化不饱和烃的硼氢化反应研究进展  

Research progress in metal-based catalysts for hydroboration of unsaturated hydrocarbons

作　　者：宋晓楠 陈颖 陕绍云[1] 支云飞 胡天丁 SONG Xiaonan;CHEN Ying;SHAN Shaoyun;ZHI Yunfei;HU Tianding(Faculty of Chemical Engineering,Kunming University of Science and Technology,Kunming 650500,Yunnan,China)

机构地区：[1]昆明理工大学化学工程学院,云南昆明650500

出　　处：《精细化工》2023年第5期978-988,共11页Fine Chemicals

基　　金：国家自然科学基金(22162016,22068023);云南省基础研究计划青年项目(202201AU070083);倪永浩院士工作站(2019IC002);云南省科技厅重大科技专项计划(202002AB080002);云南省“万人计划”基金(YNWR-QNBJ-2018-198);昆明市科学技术局科技计划基金(2019-1-G-25318000003480);昆明市科学技术局科技创新要素聚集计划重点项目(2019-1-A-24657)。

摘　　要：硼氢化反应是合成有机硼化合物的主要方式之一,因其条件温和、操作简便、原子利用率高而受到广泛关注。在过去几十年里,Rh、Ir、Pd等贵金属基材料是硼氢化反应的首选催化剂,但成本高、毒性大的特点限制了其广泛应用。近10年来,碱土金属以及Fe、Co、Ni等过渡金属因为储量丰富、价格低廉、催化效果良好,在催化硼氢化反应领域蓬勃发展,具有广阔的应用潜力。主要综述了近5年内过渡金属及碱土金属基催化剂催化不饱和烃的硼氢化反应研究进展。指出了这些金属基催化剂存在的问题,并对其未来发展方向进行了展望。Hydroboration,one of the main methods for organoboron compound synthesis,has received much attention because of its mild conditions,simple operation and high atomic utilization.Though materials containing noble metals such as Rh,Ir,and Pd have been the catalysts of primary choice for hydroboration in the past decades,their widespread applications are limited due to high cost and toxicity.In recent decade,alkaline earth metals and transition metals such as Fe,Co and Ni have been recognized in the field of catalytic hydroboration because of their abundant reserve,low price and high catalytic performance,showing broad application potential.Herein,the research progress on transition metals-based and alkaline earth metals-based catalysts for hydroboration catalysis of unsaturated hydrocarbons in five years was mainly reviewed.The existing problems and future development directions of these metal-based catalysts were also discussed.

关 键 词：硼氢化反应 催化剂 过渡金属 贵金属 廉价过渡金属 碱土金属 不饱和烃 

分 类 号：O627.31[理学—有机化学] O643.36[理学—化学]