双金属有机框架材料的研究进展  

Research progress of bimetallic⁃organic frameworks materials

作　　者：武讨龙 张胜江 刘津洋 洪晓博 李丽敏 覃晓玉 谭晓英 周燕 WU Taolong;ZHANG Shengjiang;LIU Jinyang;HONG Xiaobo;LI Limin;QIN Xiaoyu;TAN Xiaoying;ZHOU Yan(School of Chemistry and Chemical Engineering,Guangxi Minzu University,Key Laboratory of Chemistry and Engineering of Forest Products,State Ethnic Affairs Commission,Nanning 530008,China;Guangxi Key Laboratory of Chemistry and Engineering of Forest Product,Nanning 530008,China;Guangxi Collaborative Innovation Center for Chemistry and Engineering of Forest Products,Nanning 530008,China;Key Laboratory of Guangxi Colleges and Universities for Food Safety and Pharmaceutical Analytical Chemistry,Nanning 530008,China)

机构地区：[1]广西民族大学化学化工学院,林产化学与工程国家民委重点实验室,广西南宁530008 [2]广西林产化学与工程重点实验室,广西南宁530008 [3]广西林产化学与工程协同创新中心,广西南宁530008 [4]广西高校食品安全与药物分析化学重点实验室,广西南宁530008

出　　处：《无机盐工业》2023年第6期8-17,共10页Inorganic Chemicals Industry

基　　金：广西自然科学基金青年基金项目(2021JJB120110);广西科技基地与人才专项(桂科AD20238048);广西民族大学人才引进项目(2019KJQD12)。

摘　　要：双金属有机框架材料(BMOF)因其具有大的比表面积、高孔隙率、协同效应、组分和形貌可调控以及简易设计合成等特性使其在催化、生物传感、储能等诸多领域被广泛研究。综述了近年来制备双金属有机框架材料的几种常用方法,介绍了可设计与调控的形貌类型,讨论了在修饰前后的组分调控和形貌稳定性,简述了其在催化、传感、储能领域的应用性能和优势等研究进展。研究表明:双金属有机框架材料大的比表面积、双金属的协同效应、可调控的多组分和形貌,有利于孔隙率的提高、活性位点的增加、电子转移速率和性能的提高。分析了目前双金属有机框架材料所面临的挑战与存在的问题,如导电性低、合成方法单一、精准设计调控还不够成熟等。最后针对双金属有机框架材料的上述短板方面进行了展望。Bimetallicorganic frameworks materials(BMOFs)have been widely studied in many fields of catalysis,biosensing,energy storage due to their large specific surface areas,high porosities,synergistic effects,controllable components and morphologies,and easily design and synthesis,etc.The preparation of BMOFs with several common methods were reviewed.Their designed and controllable morphologies were introduced.The stability of the composition and morphology before and after modification was discussed.The application performance and advantages of BMOFs in the fields of catalysis,sensing and energy storage were briefly described.The results showed that the large specific surface areas,the synergistic effects of bimetals,the controllable multicomponents and morphologies of BMOFs were favor to the improvement of porosities,active sites,electron transfer rates and properties.And the challenges and problems were analyzed,such as low electrical conductivity,synthesis method,and insufficient maturity in precise design and regulation.Finally,the prospects based upon the above shortcomings of BMOF were proposed.

关 键 词：双金属有机框架材料 形貌 协同效应 

分 类 号：O627[理学—有机化学]