基于钌络合物催化水氧化反应中的质子传递调节:不止第二配位环境  

Proton transfer regulating in catalytic water oxidation by Ru-complexes:second coordination sphere and beyond

作　　者：刘天奇 孙立成 Tianqi Liu;Licheng Sun(Department of Chemistry,School of Engineering Sciences in Chemistry,Biotechnology and Health,KTH Royal Institute of Technology,Stockholm 10044,Sweden;Centre of Artificial Photosynthesis for Solar Fuels and Department of Chemistry,School of Science,Westlake University,Hangzhou 310024,China)

机构地区：[1]Department of Chemistry,School of Engineering Sciences in Chemistry,Biotechnology and Health,KTH Royal Institute of Technology,Stockholm 10044,Sweden [2]Centre of Artificial Photosynthesis for Solar Fuels and Department of Chemistry,School of Science,Westlake University,Hangzhou 310024,China

出　　处：《Science Bulletin》2023年第9期854-856,共3页科学通报（英文版）

基　　金：supported by the National Key R&D Program of China (2022YFA0911902);the Starting-up Package of Westlake University。

摘　　要：Proton transfer is a pivotal chemical process that occurs in a wide range of enzymatic reactions.One example is the identification of several water channels near the oxygen-evolving complex in photosystem II(OEC in PSII),which allows for substrate supply and proton release[1].

关 键 词：质子传递 钌络合物 配位环境 

分 类 号：O643.32[理学—物理化学]