Challenges of polymer electrolyte with wide electrochemical window for high energy solid-state lithium batteries  

作　　者：Sida Huo Li Sheng Wendong Xue Li Wang Hong Xu Hao Zhang Xiangming He 

机构地区：[1]School of Materials Science and Engineering,University of Science and Technology Beijing,Beijing,the People's Republic of China [2]Institute of Nuclear and New Energy Technology,Tsinghua University,Beijing,the People's Republic of China

出　　处：《InfoMat》2023年第3期102-133,共32页信息材料（英文）

基　　金：supported by the National Natural Science Foundation of China(No.U21A20170,21875284 and 22075320);the Ministry of Science and Technology of China(No.2021YFB2501900,2019YFE0100200 and 2019YFA0705703);the Fundamental Research Funds for the Central Universities(FRF-MP-20-28).

摘　　要：With the rapid development of energy storage technology,solid-state lithium batteries with high energy density,power density,and safety are considered as the ideal choice for the next generation of energy storage devices.Solid electrolytes have attracted considerable attention as key components of solid-state batteries.Compared with inorganic solid electrolytes,solid polymer electrolytes have better flexibility,machinability,and more importantly,better contact with the electrode,and low interfacial impedance.However,its low ionic conductivity,narrow electrochemical stability window(ESW),and poor mechanical properties at room temperature limit its development and practical applications.In recent years,many studies have focused on improving the ionic conductivity of polymer electrolytes;however,few systematic studies and reviews have been conducted on their ESWs.A polymer electrolyte with wide electrochemical window will aid battery operation at a high voltage,which can effectively improve their energy density.Moreover,their stability toward lithium metal anode is also important.Therefore,this review summarizes the recent progress of solid polymer electrolytes on the ESW,discusses the factors affecting ESW of polymer electrolytes,and analyzes a strategy to broaden the window from the perspective of molecular interaction,polymer structural design,and interfacial tuning.The development trends of polymer electrolytes with wide electrochemical windows are also presented.

关 键 词：electrochemical stability window molecular interaction solid polymer electrolyte structural design 

分 类 号：TM912[电气工程—电力电子与电力传动]