Recent advances in polyoxometalates acid-catalyzed organic reactions  

作　　者：Yu-Feng Liu Chang-Wen Hu Guo-Ping Yang 

机构地区：[1]Jiangxi Province Key Laboratory of Synthetic Chemistry,Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation,East China University of Technology,Nanchang 330013,China [2]Key Laboratory of Cluster Science of Ministry of Education,Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials,School of Chemistry and Chemical Engineering,Beijing Institute of Technology,Beijing 100081,China

出　　处：《Chinese Chemical Letters》2023年第5期143-154,共12页中国化学快报（英文版）

基　　金：supported by the National Natural Science Foundation of China(No.22001034);Jiangxi Provincial Natural Science Foundation(No.20212BAB213001);the Open Fund of the Jiangxi Province Key Laboratory of Synthetic Chemistry(No.JXSC202008)。

摘　　要：Polyoxometalates(POMs)have conducive properties such as controlled Bronsted and Lewis acidity,high thermal stability,nontoxic nature,tunable solubility,and less corrosiveness.POMs have been extensively applied in catalytic organic reactions and have an exciting prospect for industrial applications.This review summarized recent progress in the application of POMs as acid catalysts for various organic reactions including C-C bond formation,C-N bond formation,C-O bond formation,heterocyclic synthesis reactions,cyanosilylation and hydrolysis reactions.Various POMs catalysts including heteropoly acids(HPAs)and cationic functionalized HPAs with Bronsted acidity,HPAs supported on non-precious metal support with Bronsted acidity(or both Bronsted and Lewis acidity),transition metal substituted POMs with Lewis acidity were applied in above reactions.This review attempts to provide up-to-date information about POMs acid-catalyzed organic reactions and propose future prospects.

关 键 词：POLYOXOMETALATES Acid catalysis C-C bond formation C-N bond formation C-O bond formation Heterocyclic synthesis Cyanosilylation and hydrolysis reactions 

分 类 号：O621.251[理学—有机化学]