Highly Ordered Supramolecular Assembled Networks Tailored by Bioinspired H-Bonding Confinement for Recyclable Ion-Transport Materials  

作　　者：Chen-Yu Shi Qi Zhang Bang-Sen Wang Dan-Dan He He Tian Da-Hui Qu 

机构地区：[1]Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering,Feringa Nobel Prize Scientist Joint Research Center,Institute of Fine Chemicals,Frontiers Science Center for Materiobiology and Dynamic Chemistry,School of Chemistry and Molecular Engineering,East China University of Science and Technology,Shanghai 200237

出　　处：《CCS Chemistry》2023年第6期1422-1432,共11页中国化学会会刊（英文）

基　　金：This work was supported by the National Natural Science Foundation of China(grant nos.22025503,21790361,21788102,and 21871084);Shanghai Municipal Science and Technology Major Project(grant no.2018SHZDZX03);the Fundamental Research Funds for the Central Universities,the Programme of Introducing Talents of Discipline to Universities(grant no.B16017);Program of Shanghai Academic/Technology Research Leader(grant no.19XD1421100),Science and Technology Commission of Shanghai Municipality(grant no.21JC1401700);the Starry Night Science Fund of Zhejiang University Shanghai Institute for Advanced Study(grant no.SN-ZJU-SIAS-006).The authors thank the Research Center of Analysis and Test of East China University of Science and Technology for help on the material characterization.

摘　　要：Controlling dynamic molecular self-assembly to finely tune macroscopic properties offers chemical solutions to rational material design.Here we report that combining disulfide-mediated ring-opening polymerization withβ-sheet-like H-bonding self-assembly can drive a direct small-molecular assembly into a layered ionic network with precise architectural tunability and controllable functions as ion-transport membranes.This strategy enables a one-step evaporationinduced self-assembly from discrete small molecules to layered ionic networks with high crystallinity.The interlayer distances can be readily engineered with nanometer accuracy by varying the length of the oligopeptide side chain.The synergy of the layered structure and hydrophilic terminal groups facilitates the formation and ordering of interlayer water channels,endowing the resulting membranes with high efficiency in transporting ions.Moreover,the inherent dynamic nature of poly(disulfide)s allows chemical recycling to monomers under mild conditions.We foresee that the robust strategy of combining dynamic disulfide chemistry and noncovalent assembly can afford many opportunities in designing smart materials with unique functions and applications.

关 键 词：dynamic chemistry poly(disulfide)s β-sheet-like H-bonds ion conductivity chemical recyclability 

分 类 号：O62[理学—有机化学]