铝酸钙水泥作为耐火浇注料结合剂的研究进展  

Research Progress of Calcium Aluminate Cement as Binder for Refractory Castable

作　　者：杨建成 黄源 陈龙 苏佳淳 苑鹏 沈伯雄[1,2,3] YANG Jian-cheng;HUANG Yuan;CHEN Long;SU Jia-chun;YUAN Peng;SHEN Bo-xiong(Tianjin Key Laboratory of Clean Energy and Pollutant Control,School of Energy and Environmental Engineering,Hebei University of Technology,Tianjin 300401,China;Hebei Engineering Research Center of Pollution Control in Power System,Tianjin 300401,China;Engineering Research Center of Seawater Utilization Technology of Ministry of Education,School of Chemical Engineering,Hebei University of Technology,Tianjin 300401,China)

机构地区：[1]河北工业大学能源与环境工程学院,天津市清洁能源利用与污染物控制重点实验室,天津300401 [2]河北省动力系统污染物控制技术创新中心,天津300401 [3]河北工业大学化工学院,海水资源高效利用化工技术教育部工程研究中心,天津300401

出　　处：《科学技术与工程》2023年第16期6707-6717,共11页Science Technology and Engineering

基　　金：国家自然科学基金联合基金重点项目(U20A20302);河北省自然科学基金创新研究群体(E2021202006);河北省自然科学基金面上项目(E2022202196);河北省重大科技成果转化专项(21283701Z)。

摘　　要：耐火浇注料具有无需成型、容易施工、易于修补等优点,在高温工业领域得到广泛使用。铝酸钙水泥(calcium aluminate cement,CAC)因具有快速硬化、早期强度高、优异的抗侵蚀性能和抗磨损性能等优点,被广泛应用于浇注料中。对铝酸钙水泥的水化机理进行着重分析,对比分析多种结合剂的优缺点。从养护温度、微粉和外加剂3个方面分析铝酸钙水泥水化反应的影响因素。养护温度越高,CAC的水化程度增加,水化产物的分布越均匀。微粉和外加剂的添加可以提高水化速率并降低孔隙率。同时介绍铝酸钙水泥结合浇注料的改性方法,分析碳物质、分散剂对其施工性能和力学性能的积极作用。最后基于铝酸钙水泥结合浇注料的改性以及所面临的问题做出展望,指出探索合适的分散剂、碳物质、外加剂来提高铝酸钙水泥的水化速率、增强其结合浇注料的机械性能是今后研究的重点。Refractory castables are widely used in high-temperature industrial fields because of their advantages of no molding,easy construction,and easy repair.Calcium aluminate cement(CAC)is widely used in castables due to its advantages of rapid hardening,high early strength,excellent erosion resistance and wear resistance.The hydration mechanism of calcium aluminate cements was highlighted,and the advantages and disadvantages of various binding agents were summarized.The influencing factors of the hydration reaction of calcium aluminate cement were analyzed from three aspects:curing temperature,micropowder and admixture.The influencing factors of its hydration reaction were explained.The higher the curing temperature,the higher the degree of hydration of CAC and the more uniform the distribution of hydration products.The addition of micropowders and admixtures can increase the rate of hydration and reduce porosity.At the same time,the modification method of calcium aluminate cement combined with castable was introduced,and the positive effect of carbon material and dispersant on its construction performance and mechanical performance were analyzed.Finally,based on the modification of calcium aluminate cement combined castables and the problems faced,the outlook was made.It is pointed out that exploring suitable dispersants,carbon materials and admixtures to improve the hydration rate of calcium aluminate cement and enhance the mechanical properties of its combined castables is the focus of future research.

关 键 词：铝酸钙水泥 浇注料 结合剂 水化反应 影响因素 

分 类 号：TB35[一般工业技术—材料科学与工程]