高核稀土嵌入的多酸材料的研究进展  

Recent Advances in High-Nuclear Lanthanide-Incorporated Polyoxometalate Materials

作　　者：林玉雕 郑寿添 李新雄 Lin Yudiao;Zheng Shoutian;Li Xinxiong(Fujian Provincial Key Lab of Coastal Basin Environment,College of Materials and Package Engineering,Fujian Polytechnic Normal Univeristy,Fuqing 350300,China;Fujian Provincial Key Laboratory of Advanced Inorganic Oxygenated Materials,State Key Laboratory of Photocatalysis on Energy and Environment,College of Chemistry,Fuzhou University,Fuzhou 350108,China)

机构地区：[1]福建技术师范学院材料与包装工程学院,近海流域环境测控治理福建省高校重点实验室,福建福清350300 [2]福州大学化学学院,福建省先进无机氧合材料重点实验室,福建福州350108

出　　处：《中国稀土学报》2023年第3期541-570,I0004,共31页Journal of the Chinese Society of Rare Earths

基　　金：国家自然科学基金项目(92161108,22171045);福建省自然科学基金项目(2020J01130120)资助。

摘　　要：高核稀土嵌入的多酸材料是近年来无机合成化学与材料化学领域的研究热点。由于稀土离子独特的电子排布和结构特征以及多酸材料的优异特性,赋予了该类材料在催化、磁学、电化学、传感探针和医药等领域重要的应用前景。本文围绕着近30年来高核稀土嵌入的多酸材料的研究进展,分别对该类材料的合成策略、结构类型、结构调控、相关性质等方面进行了详细阐述。此外,还对当前该类材料的发展所面临的挑战进行了总结,并对其应用发展提出了展望。High-nuclear rare-earth incorporated polyoxometalates(POMs) have been a research hotspot in the fields of inorganic synthetic chemistry and material chemistry. Due to the unique electronic arrangement and the structural characteristics of the rare earth ions and the excellent properties of POMs, these materials have promising application in catalysis, magnetism, electrochemistry, sensor probes and medicine etc. In this review, the research advance of high-nuclear rare earth incorporated POMs in the past three decades including their synthetic strategies, structural diversity, structure modulation, and related properties is summarized. In addition, the current challenges in this area and the prospects of their application are also discussed.

关 键 词：金属-氧簇 稀土簇 多酸 催化 磁性 

分 类 号：O612.33[理学—无机化学]