Insight into relationship between composition,thickness and electrochemistry behavior of oxide film formed on TA15under different potentials in 0.5 mol·L^(-1)H_(2)SO_(4)  

作　　者：Fei-Fei Huang Yi Qin Qing-Rui Wang Hiroaki Yoshida Lei Wen Hai Chang Ying Jin 

机构地区：[1]National Center for Materials Service Safety,University of Science and Technology Beijing,Beijing,100083,China [2]Innovation Group of Marine Engineering Materials and Corrosion Control,Southern Marine Science and Engineering Guangdong Laboratory,Zhuhai,519080,China [3]Department of Physical Science,Hiroshima University,Higashi-Hiroshima,739-8526,Japan

出　　处：《Rare Metals》2023年第5期1760-1772,共13页稀有金属（英文版）

基　　金：financially supported by the National Key Research and Development Program of China(No.2022YFA1603803);the Innovation Group Project of Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)(No.311021013);the support from National Foreign Experts Program(No.G2021105010L)in China for promoting international exchange。

摘　　要：The oxide film formed on TA15 alloy in0.5 mol·L^(-1)H_(2)SO_(4)at different applied potentials is investigated by evaluating the film formation current density,film thickness,surface film composition,valence state,and the electrochemical characteristics.The relative quantitative spectral analysis revealed by X-ray photoelectron spectroscopy(XPS)and X-ray absorption spectra(XAS)shows that the increasing applied potential promotes the formation of thick and high-valence state films.By contrasting with XAS of the reference titanium oxides,it is found that TiO_(2)within the oxide film changes from anatase type to rutile type with the potential increases to 2.00 V.The oxide film formed at passive region has better protection performance,and with the increase of applied potential,the corrosion resistance of passive film increases,whereas the ND(donor density)values obtained from the Mott-Schottky(MS)results decrease with the increasing applied potential,indicating a better uniformity and protective effect of the oxide film.Based on above facts,the model of the oxide films formed on TA15 at different applied potentials in passive region and dissolve region is proposed.Besides,the existence forms of all the TA15alloying elements under the most corrosion resistant condition are confirmed.

关 键 词：TA15 Electrochemical passivation Corrosion behavior Surface compositions and structures 

分 类 号：TG174.4[金属学及工艺—金属表面处理]